(η1:η5-cyclo-C4H8NC2H4C5Me4)CrMe2 | 202843-41-2

• 英文名称: (η1:η5-cyclo-C4H8NC2H4C5Me4)CrMe2
• CAS: 202843-41-2
• 化学式: C₁₇H₃₀CrN
• 分子量: 300.428
• InChiKey: CERXKWVNSNEQJT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  tetrakis[3,5-bis(trifluoromethyl)phenyl]boric acid bis(diethyl ether) complex 、 (η1:η5-cyclo-C4H8NC2H4C5Me4)CrMe2 以 乙醚 为溶剂， 以78%的产率得到[(η1:η5-cyclo-C4H8NC2H4C5Me4)CrMe][B(C6H3(CF3)2-3,5)4]*0.5Et2O
  参考文献：
  名称：

  Donor-Ligand-Substituted Cyclopentadienylchromium(III) Complexes:  A New Class of Alkene Polymerization Catalyst. 1. Amino-Substituted Systems

  摘要：

  Me2NC2H4C5Me4Li reacts with Cr(THF)(3)Cl-3 to give (eta(1):eta(5)-Me2NC2H4C5Me4) CrCl2, in which the complexation of the N-donor atom to the metal atom has been confirmed by X-ray crystallography. A series of related compounds, e.g. (eta(1):eta(5)-cyclo-C4H8NSiMe2OSiMe2C5H4)-CrCl2 has been prepared by varying the substituents on the organic ligand. Further reaction with organomagnesium reagents leads to formation of the corresponding dialkyl-Cr complexes. Related species have been prepared containing imine-, alkoxy-, and alkylthiosubstituted cyclopentadienyl groups as well as the C-donor ligand tetramethylimidazol-2-ylidene. Treatment of these compounds with methylalumoxane (MAO) leads to the formation of highly active catalysts for the oligomerization, polymerization, and copolymerization of ethylene.

  DOI：

  10.1021/om990643r
• 作为产物：
  描述：

  trichlorotris(tetrahydrofuran)chromium(III) 、 甲基氯化镁 、 sodium [3-(dimethylamino)propyl]cyclopentadienide 以 四氢呋喃 为溶剂， 以86%的产率得到(η1:η5-cyclo-C4H8NC2H4C5Me4)CrMe2
  参考文献：
  名称：

  Donor-Ligand-Substituted Cyclopentadienylchromium(III) Complexes:  A New Class of Alkene Polymerization Catalyst. 1. Amino-Substituted Systems

  摘要：

  Me2NC2H4C5Me4Li reacts with Cr(THF)(3)Cl-3 to give (eta(1):eta(5)-Me2NC2H4C5Me4) CrCl2, in which the complexation of the N-donor atom to the metal atom has been confirmed by X-ray crystallography. A series of related compounds, e.g. (eta(1):eta(5)-cyclo-C4H8NSiMe2OSiMe2C5H4)-CrCl2 has been prepared by varying the substituents on the organic ligand. Further reaction with organomagnesium reagents leads to formation of the corresponding dialkyl-Cr complexes. Related species have been prepared containing imine-, alkoxy-, and alkylthiosubstituted cyclopentadienyl groups as well as the C-donor ligand tetramethylimidazol-2-ylidene. Treatment of these compounds with methylalumoxane (MAO) leads to the formation of highly active catalysts for the oligomerization, polymerization, and copolymerization of ethylene.

  DOI：

  10.1021/om990643r