1,1'-bis(diisopropylboryl)cobaltocene | 177956-54-6

• 英文名称: 1,1'-bis(diisopropylboryl)cobaltocene
• CAS: 177956-54-6
• 化学式: C₂₂H₃₆B₂Co
• 分子量: 381.143
• InChiKey: XPRSAXCZNUKDIK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  1,1'-bis(diisopropylboryl)cobaltocene 、 copper(l) chloride 生成 1-(diisopropylboryl)-1'-(diisopropylchloroboryl)cobaltocenium
  参考文献：
  名称：

  Bis(boryl)metallocenes. 1. 1,1‘-Bis(diisopropylboryl)cobaltocenium Cation:  A Novel Anion-Binding Ligand

  摘要：

  Three situations are observed when the new cobaltocene derivative Co(C5H4BPr2i)(2) (2) is oxidized. The cobaltocenium salt [2]PF6 (3) is obtained with [FeCp(2)]PF6 as oxidant. With Cu(OH)(2) the inverse chelate [2]OH (4) with a mu-OH group bridging the two boron centers is formed. Oxidation with C2Cl6 gives a zwitterionic chloride (5) with a trigonal and a quaternized boron center; in solution 5 is fluxional.

  DOI：

  10.1021/om960237x
• 作为产物：
  描述：

  CoBr₂*1.18DME 、 cyclopentadienyldiisopropylborane 在 LiCp 作用下， 以 四氢呋喃 为溶剂， 以98%的产率得到1,1'-bis(diisopropylboryl)cobaltocene
  参考文献：
  名称：

  Bis(boryl)metallocenes. 1. 1,1‘-Bis(diisopropylboryl)cobaltocenium Cation:  A Novel Anion-Binding Ligand

  摘要：

  Three situations are observed when the new cobaltocene derivative Co(C5H4BPr2i)(2) (2) is oxidized. The cobaltocenium salt [2]PF6 (3) is obtained with [FeCp(2)]PF6 as oxidant. With Cu(OH)(2) the inverse chelate [2]OH (4) with a mu-OH group bridging the two boron centers is formed. Oxidation with C2Cl6 gives a zwitterionic chloride (5) with a trigonal and a quaternized boron center; in solution 5 is fluxional.

  DOI：

  10.1021/om960237x