| 1451218-13-5

• CAS: 1451218-13-5
• 化学式: C₂₇H₄₄Cl₆N₄O₂W
• 分子量: 853.24
• InChiKey: VHJYIGNLMVHXII-UHFFFAOYSA-I

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二氧化碳 、 六氯化钨 、 N,N'-二环己基碳二亚胺 以 1,2-二氯乙烷 为溶剂， 生成
  参考文献：
  名称：

  Synthesis of carboxylate derivatives of molybdenum and tungsten based on joint insertion of CO2 and PhNCS or N, N′-dicyclohexylcarbodiimide into M-Cl bonds

  摘要：

  Reactions of the higher molybdenum and tungsten chlorides with phenyl isothiocyanate or with N,N'-dicyclohexylcarbodiimide and carbon dioxide in dichloroethane are the first to demonstrate the possibility of insertion of carbon dioxide in combination with other heterocumulenes into transition metal-halogen bonds. IR spectroscopy and elemental analysis data show that the reactions result in the attachment of the ligands at the same metal-chlorine bond and the formation of heteromolecular insertion products with the compositions[MoOCl3{N(Ph)C(S)}(2)NC(Me)Cl]andMClx{OC(O)[(Hex)NCN(Hex)](2)}Cl,where x = 4 and 5 for the Mo and W derivatives, respectively.

  DOI：

  10.1134/s0020168513050105