| 190390-99-9

• CAS: 190390-99-9
• 化学式: C₁₃H₁₄FeNO₂P
• 分子量: 303.08
• InChiKey: KYPYWFMOGSPECP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 sodium tetrahydroborate 在 NiCl₂*6H₂O 作用下， 以 四氢呋喃 、 甲醇 为溶剂， 以89%的产率得到
  参考文献：
  名称：

  A New Concept for Chelate Ligands with Planar Chirality

  摘要：

  The chiral donor substituted phosphaferrocene derivatives CpFe(3,4-Me-2-2-R-C4HP) 6 (R = CH2CH2NMe2), 7 (R = CH2NMe2), and 8 (R = CH2OPPh2) were synthesized as racemates starting from 2-formyl-3,4-dimethylphosphaferrocene. The P,N-ligand 6 reacted with [Cp*RuCl](4) in THF to give the six-ring chelate complex Cp*RuCl(6) (=10) which was characterized by single-crystal X-ray diffraction analysis. The complexation reaction was found to proceed diastereoselectively with respect to the newly created stereogenic center on the ruthenium atom. Under similar conditions, the reaction of ligand 7 with [Cp*RuCl](4) did not lead to chelate formation. Instead, two isomers of the bis-P-coordinated complex Cp*RuCl(7)(2) (=11) were observed by NMR spectroscopy. Reaction of the phosphinite ligand 8 with (PhCN)(2)PdCl2 in toluene produced the six-ring chelate complex cis-PdCl2(8) (=12). The crystal structure of 12 has been determined.

  DOI：

  10.1021/om970059n
• 作为产物：
  描述：

  硝基甲烷 、 (3,4-dimethylphosphaferrocen-2-yl)carbaldehyde 以 甲醇 为溶剂， 以78%的产率得到
  参考文献：
  名称：

  A New Concept for Chelate Ligands with Planar Chirality

  摘要：

  The chiral donor substituted phosphaferrocene derivatives CpFe(3,4-Me-2-2-R-C4HP) 6 (R = CH2CH2NMe2), 7 (R = CH2NMe2), and 8 (R = CH2OPPh2) were synthesized as racemates starting from 2-formyl-3,4-dimethylphosphaferrocene. The P,N-ligand 6 reacted with [Cp*RuCl](4) in THF to give the six-ring chelate complex Cp*RuCl(6) (=10) which was characterized by single-crystal X-ray diffraction analysis. The complexation reaction was found to proceed diastereoselectively with respect to the newly created stereogenic center on the ruthenium atom. Under similar conditions, the reaction of ligand 7 with [Cp*RuCl](4) did not lead to chelate formation. Instead, two isomers of the bis-P-coordinated complex Cp*RuCl(7)(2) (=11) were observed by NMR spectroscopy. Reaction of the phosphinite ligand 8 with (PhCN)(2)PdCl2 in toluene produced the six-ring chelate complex cis-PdCl2(8) (=12). The crystal structure of 12 has been determined.

  DOI：

  10.1021/om970059n