| 73769-66-1

• CAS: 73769-66-1
• 化学式: C₁₄H₂₆Cl₂Pd₂
• 分子量: 478.106
• InChiKey: YKQGQDPYVMBMTM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 pentamethylcyclopentadienyllithium 以 正戊烷 为溶剂， 生成
  参考文献：
  名称：

  Werner; Crisp; Jolly, Organometallics, 1983, vol. 2, # 10, p. 1369 - 1377

  摘要：

  DOI：

文献信息

• Bis(β-diketonato)- and allyl-(β-diketonato)-palladium(<scp>ii</scp>) complexes: synthesis, characterization and MOCVD application
  作者：K. Assim、M. Melzer、M. Korb、T. Rüffer、A. Jakob、J. Noll、C. Georgi、S. E. Schulz、H. Lang

  DOI：10.1039/c6ra22887a

  日期：——

  palladium layer formation. Thermogravimetric studies showed the evaporation of the complexes at atmospheric pressure upon heating. The vapor pressure of 7, 8 and 11–14 was measured by using thermogravimetric analysis, giving vapor pressure values ranging from 0.62 to 2.22 mbar at 80 °C. Chemical vapor deposition studies were carried out applying a vertical cold wall CVD reactor. Either oxygen or forming

  钯配合物[钯（ACCP）的合成和表征2 ]（7），[钯（ACCH）2 ]（8），[将Pd（η 3 -CH 2 CMeCH 2）（ACCP）]（11），[加入Pd（η 3 -CH 2 CMeCH 2）（ACCH）]（12），[将Pd（η 3 -CH 2 ç吨布赫2）（ACCP）]（13）和[加入Pd（η 3 -CH 2 C ^吨布赫2）（acch）]（14）（acCP = 2-乙酰基环戊酸酯; acch = 2-乙酰基环己酸酯）。这些复合物可用由HACCP（2- acetylcyclopentanone）和Hacch（2-乙酰基）的用Na反应2 [的Pd 2氯6 ]形成7和8或[（加入Pd（η 3 -CH 2 CRCH 2）（μ -Cl））2 ]（9，R = Me；10，R = t Bu）形成11–14。的分子结构7，8和14进行了讨论。配合物7和8由具有两个正方形平面协调的Pd原子的反式-
• Werner, Helmut; Kraus, Hans-Juergen, Chemische Berichte, 1980, vol. 113, # 3, p. 1072 - 1083
  作者：Werner, Helmut、Kraus, Hans-Juergen

  DOI：——

  日期：——
• Synthese von π-allyl-palladium-komplexen, stabilisiert durch dreizähnige sauerstoffliganden [(C5H5)Co{P(OR)2O}3]−
  作者：Bernd Domhöver、Harry Hamers、Wolfgang Kläui、Michel Pfeffer

  DOI：10.1016/0022-328x(96)06252-3

  日期：1996.9

  Complexes of the general formula [(C5H5)CoP(OR)(2)O}(3)}Pd(all)]=[L(OR)Pd(all)] (1-4) (OR=OMe, OEt; all=propenyl, 2-methyl-propenyl, 2-(t)butylpropenyl, 1,1,2-trimethylpropenyl) have been synthesized from the corresponding silver salt AgL(OR) and the dimeric pi-allyl-palladium complexes [(all)PdCl}(2)]. These air-stable compounds are the first examples of 18-electron pi-allyl-palladium complexes stabilized by a tripodal oxygen donor, The X-ray structure of [L(OMe)Pd(C3H5)}(2) . H2O] has been determined. The compound crystallizes in the monoclinic space group P2(1)/c with a=17.046(7), b=31.527(9), c=10.772(3) Angstrom, beta=127.71(4)degrees, Z=4. Two of the three oxygen donor atoms of the ligand coordinate strongly to palladium while the third in addition forms a hydrogen bond to a water molecule. The palladium-oxygen interatomic distances are Pd1-O3=2.138(3), Pd1-O2=2.151(2), Pd1-O1=2.622(2), Pd2-O6=2.129(3), Pd2-O4=2.143(3) and Pd2-O5=2.689(3).
• Werner, Helmut; Ngo-Khac, Tri; Friebel, Claus, Zeitschrift fur Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1981, vol. 36, # 3, p. 322 - 331
  作者：Werner, Helmut、Ngo-Khac, Tri、Friebel, Claus、Koehler, Peter、Reinen, Dirk

  DOI：——

  日期：——