(1,3,7-trimethyl-2,6-dioxo-2,3,6,7-tetrahydro-1H-purin-8-yl)tris(trimethyl-l5-phosphaneyl)cobalt(V) bromide | 1428543-96-7

• 英文名称: (1,3,7-trimethyl-2,6-dioxo-2,3,6,7-tetrahydro-1H-purin-8-yl)tris(trimethyl-l5-phosphaneyl)cobalt(V) bromide
• CAS: 1428543-96-7
• 化学式: C₁₇H₃₆BrCoN₄O₂P₃
• 分子量: 560.317
• InChiKey: JDRFDRDESQNKSR-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  methyltetrakis(trimethylphosphine)cobalt(I) 以 乙醚 、 正戊烷 为溶剂， 反应 34.0h， 生成 (1,3,7-trimethyl-2,6-dioxo-2,3,6,7-tetrahydro-1H-purin-8-yl)tris(trimethyl-l5-phosphaneyl)cobalt(V) bromide
  参考文献：
  名称：

  Cobalt induced CH bond activation and C8-arylation of caffeine with aryl bromides

  摘要：

  The 8-caffeinyl cobalt(I) complex (C8-caffeinyl)Co(PMe3)(4) (1) was obtained by reaction of caffeine with cobalt(I) complex CoMe(PMe3)(4) via C-H bond activation with the escape of methane. The reaction of I with arylbromide afforded cobalt(II) complex (C8-caffeinyl)Co(PMe3)(3)Br (2) and the C,C-coupling products 8-aryl caffeine (3 and 4), 8-phenyl caffeine and 8-(2'-pyridinayl)caffeine. The crystal structures of complexes 1 and 2 were determined by X-ray diffraction. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2013.01.025