[Fe(η5-C5H4)2(μ-PNtBu)2] | 950835-63-9

• 英文名称: [Fe(η5-C5H4)2(μ-PNtBu)2]
• 英文别名: 1,3-di-tert-butyl-2,4-bis(cyclopentadienyl)iron(II) 1,3,2,4-diazadiphosphetidine；diphosphaferrocenophane；[Fe(η⁵-C₅H₄)₂(μ-PN^tBu)₂]；[Fe(η⁵-C₅H₄)₂(PN^tBu)₂]；[Fe(η⁵-C5H4)₂(PN^tBu)₂]；[Fe(η5-C5H4)2(PNtBu)2]
• CAS: 950835-63-9
• 化学式: C₁₈H₂₆FeN₂P₂
• 分子量: 388.212
• InChiKey: QNWGEVYNVKQBOB-WHXBIKBMSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [Fe(η5-C5H4)2(μ-PNtBu)2] 、 chloro(1,5-cyclooctadiene)rhodium(I) dimer 以 二氯甲烷 为溶剂， 反应 5.0h， 以69%的产率得到[{RhCl(COD)}₂{Fe(η⁵-C₅H₄)₂(μ-PN^tBu)₂}]
  参考文献：
  名称：

  Bischalcogenides and transition metal complexes of cyclodiphosphazane derived diphosphaferrocenophane

  摘要：

  Oxidation reactions and transition metal chemistry of diphosphaferrocenophane [Fe(eta(5)-C5H4)(2)(mu-(PNBu)-Bu-t)(2)] (1) has been reported. The reactions of 1 with aq. H2O2 and elemental selenium afforded bis-chalcogenides, [Fe(eta(5)-C5H4)(2)(mu-P(E)(NBu)-Bu-t)(2)] (E = O; 2, E = Se; 3). Treatment of 1 with [Rh(COD)Cl](2) and [Pd(eta(3)-C3H5)Cl](2) in 1:1 molar ratio afforded binuclear complexes, [(RhCl(COD))(2)(Fe(eta(5)-C5H4)(2)(mu-(PNBu)-Bu-t)(2))] (4) and [[Pd(eta(3)-C3H5)Cl}(2)Fe(eta(5)-C5H4)(2)(mu-(PNBu)-Bu-t)(2)}] (5), respectively. The mixed-ligand binuclear Cu-I complex [{(2,2'-bpy)CuI)(2){Fe(eta(5)-C5H4)(2)(mu-(PNBu)-Bu-t)(2)}] (6) was synthesized by the reaction of 1 with Cul followed by treatment with 2,2'-bipyridine. The reaction between 1 and [AuCl(SMe2)] in 1:2 molar ratio yielded the dinuclear complex [(AuCl)(2){Fe(eta(5)-C5H4)(2)(mu-(PNBu)-Bu-t)(2)}] (7) showing intermolecular aurophilic interactions in the crystal lattice. The crystal structures of 2, 4-7 were established by single-crystal X-ray diffraction studies. (C) 2015 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2015.08.043
• 作为产物：
  描述：

  二茂铁 、 2,4-dichloro-1,3-di-tert-butyl-1,3,2,4-diazadiphosphetidine 在 n-BuLi 、 Me₂NC₂H₄NMe₂ 作用下， 以 乙醚 、 正己烷 为溶剂， 以55%的产率得到[Fe(η5-C5H4)2(μ-PNtBu)2]
  参考文献：
  名称：

  Synthesis and Molecular Structure of 1,3-Di-tert-butyl-2,4-bis(cyclodipentadienyl)iron(II) 1,3,2,4-Diazadiphosphetidine, [Fe(η⁵-C₅H₄)₂(PN^tBu)₂]

  摘要：

  The reaction of the dichlorocyclodiphosphazane (also called dichlorodiazadiphosphetidine), [ClP(mu-(NBu)-Bu-t)](2), with in situ generated ferrocene dilithiate in a 1:1 molar ratio affords the first metallocene derivative of a diazadiphosphetidine, 1,3-di-tert-butyl-2,4-bis(cyclopentadienyl)iron(II) 1,3,2,4-diazadiphosphetidine, [Fe(eta(5)-C5H4)(2)((PNBu)-Bu-t)(2)], in good yield.

  DOI：

  10.1021/om700423h

文献信息

• Novel zeotype frameworks with soft cyclodiphosphazane linkers and soft Cu₄X₄ clusters as nodes
  作者：Mujahuddin M. Siddiqui、Shaikh M. Mobin、Irena Senkovska、Stefan Kaskel、Maravanji S. Balakrishna

  DOI：10.1039/c4cc03810j

  日期：——

  Two novel zeolitic phosphane cluster frameworks have been synthesized by using ferrocenyl cyclodiphosphazanes [Fe(η⁵-C₅H₄)₂P(μ-N^tBu)}₂] as ditopic linkers and [Cu₄X₄] clusters as tetrahedral nodes.

  使用二茂铁基环二磷氮杂环簇合物[Fe(η⁵-C₅H₄)₂P(μ-N^tBu)}₂]作为二元配体和[Cu₄X₄]簇合物作为四面体节点，合成了两种新型的沸石磷簇合物框架。
• Cyclodiphosphazanes in metal organic frameworks
  作者：M. S. Balakrishna

  DOI：10.1080/10426507.2015.1128906

  日期：2016.4.2

  GRAPHICAL ABSTRACT ABSTRACT The reactivity of cyclodiphosphazanes towards various transition metal derivatives has been studied. The products obtained showed simple monomeric to di-, tetra-, or pentameric structures. The interactions between cyclodiphosphazanes and copper halides resulted in the formation of several one-dimensional (1D), 2D, or 3D coordination polymers having adamantanoid, diamondoid

  图形摘要 已研究了环二磷氮烷对各种过渡金属衍生物的反应性。获得的产品显示出简单的单体到二聚体、四聚体或五聚体结构。环二磷氮烷和卤化铜之间的相互作用导致形成了几种具有金刚烷、金刚石或方钠石结构的一维 (1D)、2D 或 3D 配位聚合物，这在均配软金属-软配体组合中很少见。