{tetracarbonyl rhenium-diethylether-(tetrafluoroborate)} | 149477-32-7

• 英文名称: {tetracarbonyl rhenium-diethylether-(tetrafluoroborate)}
• CAS: 149477-32-7
• 化学式: C₈H₁₀BF₄O₅Re
• 分子量: 459.176
• InChiKey: SMCYBLHTSJLOAI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  {tetracarbonyl rhenium-diethylether-(tetrafluoroborate)} 、 potassium oxalate 在 sodium hydroxide 作用下， 以 水 为溶剂， 以12%的产率得到oxalatobis(tetracarbonylrhenium(H2O)2)
  参考文献：
  名称：

  Metallorganische Lewis-Sa¨uren

  摘要：

  The complex [(OC)(4)Re(OH2)(2)](+) reacts with oxalate and squarate to give the complexes [(OC)(4)Re(OH2)2]C2O4 (1) and [(OC)(4)Re(OH2)(2)]C4O4 (2). The reaction of (OC)(2)(PPh(3))(2)Ru(FBF3)(2) with potassium salts of cu-aminoacids (glycine, L-alanine, L-phenylalanine) yields cationic ruthenium complexes with chelating aminoacidates (3-5). With acetylacetonate the complex [(OC)(2)(PPh(3))(2)Ru(acac)I[BF4] (16) is obtained. Nitriles and isonitriles give the complexes [(OC)(4)Re(N=C-R)(2)][BF4] (6: R = Me; 7: R = CH(2)CO(2)Et), [(OC)(2)(PPh(3))(2)Ru(N=C-R)(2)I[BF4](2) (8: R = Me, 9: R = p-C(6)H(4)OMe), [(OC)(4) Re(C=N-R)(2)][BF4] (10: R = (CH2)(3)Me; 11: R = CH(2)CO(2)Et) and [(OC)(2)(PPh(3))(2)Ru(C=N-R)2][BF4](2) (12: R = CH(2)CO(2)Et; 13: R = C6H11), respectively. With thioethers (OC)(4)Re(OEt(2))FBF3 forms the complexes [(OC)(4)Re(Ph-S-CH2-S-Ph)][BF4] (14) and [(OC)(4) Re(HO-(CH2)(2)-S(CH2)(2)-S-(CH2)(2)OH)][BF4] (15).

  DOI：

  10.1016/0022-328x(94)88043-3
• 作为产物：
  描述：

  四氟硼酸-二乙醚络合物 、 (OC)4Re(η(3)-C3H5) 以 二氯甲烷 为溶剂， 生成 {tetracarbonyl rhenium-diethylether-(tetrafluoroborate)}
  参考文献：
  名称：

  Metallorganische Lewis-Sa¨uren

  摘要：

  The complex [(OC)(4)Re(OH2)(2)](+) reacts with oxalate and squarate to give the complexes [(OC)(4)Re(OH2)2]C2O4 (1) and [(OC)(4)Re(OH2)(2)]C4O4 (2). The reaction of (OC)(2)(PPh(3))(2)Ru(FBF3)(2) with potassium salts of cu-aminoacids (glycine, L-alanine, L-phenylalanine) yields cationic ruthenium complexes with chelating aminoacidates (3-5). With acetylacetonate the complex [(OC)(2)(PPh(3))(2)Ru(acac)I[BF4] (16) is obtained. Nitriles and isonitriles give the complexes [(OC)(4)Re(N=C-R)(2)][BF4] (6: R = Me; 7: R = CH(2)CO(2)Et), [(OC)(2)(PPh(3))(2)Ru(N=C-R)(2)I[BF4](2) (8: R = Me, 9: R = p-C(6)H(4)OMe), [(OC)(4) Re(C=N-R)(2)][BF4] (10: R = (CH2)(3)Me; 11: R = CH(2)CO(2)Et) and [(OC)(2)(PPh(3))(2)Ru(C=N-R)2][BF4](2) (12: R = CH(2)CO(2)Et; 13: R = C6H11), respectively. With thioethers (OC)(4)Re(OEt(2))FBF3 forms the complexes [(OC)(4)Re(Ph-S-CH2-S-Ph)][BF4] (14) and [(OC)(4) Re(HO-(CH2)(2)-S(CH2)(2)-S-(CH2)(2)OH)][BF4] (15).

  DOI：

  10.1016/0022-328x(94)88043-3

文献信息

• Kraemer, Roland; Lippmann, Elisabeth; Noisternig, Karin, Chemische Berichte, 1993, vol. 126, # 4, p. 927 - 932
  作者：Kraemer, Roland、Lippmann, Elisabeth、Noisternig, Karin、Steimann, Manfred、Nagel, Ulrich、Beck, Wolfgang

  DOI：——

  日期：——