| 1417815-59-8

• CAS: 1417815-59-8
• 化学式: C₁₆H₁₈Cl₂CoN₈O₂
• 分子量: 484.271
• InChiKey: XSXYLOZSDCFZSK-MYHDMYFSSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  联苯甲酰 在 溶剂黄146 作用下， 以 乙醇 、 水 为溶剂， 反应 2.25h， 生成
  参考文献：
  名称：

  Synthesis, structural and fungicidal studies of hydrazone based coordination compounds

  摘要：

  The coordination compounds of the Co(II), Ni(II) and Cu(II) metal ions derived from imine based ligand, benzil bis(carbohydarzone) were structurally and pharmaceutically studied. The compounds have the general stoichiometry [M(L)]X-2 and [Co(L)X-2], where M = Ni(II) and Cu(II), and X = NO3- and Cl(-)ions. The analytical techniques like elemental analyses, molar conductance measurements, magnetic susceptibility measurements, IR, UV/Visible, NMR, ESI mass and EPR were used to study the compounds. The key IR bands, i.e., amide I, amide II and amide III stretching vibrations accounts for the tetradentate metal binding nature of the ligand. The electronic and EPR spectral results suggest the square planar Ni(II) and Cu(II) complexes (g(iso) = 2.11-2.22) and tetragonal geometry Co(II) complexes (g(iso) = 2.10-2.17). To explore the compounds in the biological field, they were examined against the opportunistic pathogens, i.e., Alternaria brassicae, Aspergillus niger and Fusarium oxysporum. The partial covalent character of metal-ligand bond is supported by the orbital reduction factor k (0.62-0.92) and nephalauxetic parameter beta (0.55-0.57). (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2012.11.012