[Pd(2-aminothiolate)2] | 53496-01-8

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属有机体
• 英文名称: [Pd(2-aminothiolate)2]
• 英文别名: [Pd(2-aminoethanethiolate)2]；2-aminoethanethiolate;palladium(2+)
• CAS: 53496-01-8；67225-29-0；36545-44-5
• 化学式: C₄H₁₂N₂PdS₂
• 分子量: 258.705
• InChiKey: FYVYFHCUOSZVHE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Pd(2-aminothiolate)2] 、 [Ag2(bis(diphenylphosphino)methane)2(acetonitrile)2](SbF6)2 以 乙腈 为溶剂， 以62%的产率得到Ag2Pd(μ-bis(diphenylphosphino)methane)2(μ-aminoethanethiolate)2)(SbF6)2*CH3CN
  参考文献：
  名称：

  Self-assembly luminescent heteroheptanuclear complexes with metal diphosphine and metal thiolate as components

  摘要：

  [M2(μ-dppm)2(MeCN)2]2+（M = Cu或Ag；dppm = 双(二苯基膦)甲烷）和M′(aet)2（aet = 2-氨基乙硫醇）之间的自组装产生了发光的异七核配合物[Cu4M′3(μ-dppm)3(μ3-aet)4(μ-aet)2]4+（M′ = Ni 1；Pd 2）或异三核配合物[Ag2M′(μ-dppm)2(μ-aet)2]2+（M′ = Ni 3；Pd 4）。

  DOI：

  10.1039/b204369f
• 作为产物：
  描述：

  sodium tetrachloropalladate(II) 、 fac-tris(2-aminoethanethiolate)cobalt(III) 、 sodium chloride 以 水 为溶剂， 以35%的产率得到[Pd2(Pd(2-aminoethanethiolate)2)(Co(2-aminoethanethiolate)3)2]Cl4 * 5.5 H2O
  参考文献：
  名称：

  Stereoselectivity for S-Bridged Polynuclear Transition Metal Complexes Formed by Aggregation of Octahedral Complexes to Square-Planar Palladium(II)

  摘要：

  新型五核配合物[Pd{Pd(aet)}{M(aet)2}{M(aet)3}2]4+（M = Rh (1)；Ir (2)；aet = 2-氨基乙硫醇）和[Pd2{Pd(aet)2}{Co(aet)3}2]4+ (4)，是由面(S)-[M′(aet)3]（M′ = M、Co）与 Na2[PdCl4] 反应制备的。通过 X 射线衍射确定了 1、2 和 4 的分子结构。在 1 和 2 中，由两个八面体面（S）-[M(aet)3] 单元和顺（N）-[M(S)2(aet)2] 单元聚合而成的两个钯原子构成平行面。在这些配合物中，起始面（S）-[M（aet）3] 中的一个 aet 配体从 M（= Rh、Ir）原子转移到了钯原子上。4 中的两个钯原子由两个面（S）-[Co(aet)3] 单元和顺（S）-[Pd(aet)2] 单元桥接。在该配合物中，两个 aet 配体转移到了钯配体上。1 中一个非桥接 S 原子的甲基化反应产生了相应的配合物 [Pd{Pd(aet)}{Rh(aet)(smaet}{Rh(aet)3}2]5+ (3; smaet = S-甲基-2-氨基乙硫醇酸盐)，其结构也通过 X 射线衍射确定。所有这些配合物的手性构型都是通过八面体单元（Δ 或 Λ）和桥接硫原子（R 或 S）进行选择性调节的，并根据电子吸收、圆二色（CD）和 13C NMR 光谱行为对其进行了表征。此外，还讨论了 1、2 和 4 中八面体单元的结合模式与其立体化学行为的关系。

  DOI：

  10.1246/bcsj.72.1685

文献信息

• Structural Characteristics of<b><i>S</i></b>-Bridged Trinuclear Complexes [{Pd(terpy)}₂{Pd(aet)₂}]⁴⁺(terpy = 2,2^′: 6^′,2^′′-Terpyridine, aet = 2-Aminoethanethiolate): Effects of Counter Anions and Solvent on Intra- and Intermolecular Stacking Arrangements
  作者：Yasunori Yamada、Kiyoshi Fujisawa、Ken-ichi Okamoto

  DOI：10.1246/bcsj.73.2297

  日期：2000.10

  S-bridged trinuclear Pd(II) complexes, [Pd(terpy)}2Pd(aet)2}]X4·nSolv (terpy = 2,2′ : 6′,2′′-terpyridine, aet = 2-aminoethanethiolate; X = PF6-, n = 2, Solv = CH3CN (1); X = BF4-, n = 0.5, Solv = H2O (2); X = BF4-, n = 0 (3); 2X = SiF62-, n = 6, Solv = H2O (4)), were obtained by the reactions of [Pd(aet)2] (aet = 2-aminoethanethiolate) with [Pd(NO3)(terpy)]+ (terpy = 2,2′ : 6′,2′′-terpyridine) using some kinds of counter anions and solvents. The molecules of 1—4, whose structures were determined by X-ray crystallography, contain two Pd(terpy)} moieties bridged by one [Pd(aet)2] unit. Although the molecular structures of these complexes are similar to each other, they have significantly different intermolecular structures from each other. While 1 and 2 take monomeric structures, 3 and 4 exist as polymeric forms. These structural features also reflect their diffuse reflection spectra.

  S-桥联的三核Pd(II)配合物[Pd(terpy)}2Pd(aet)2}]X4·nSolv（terpy = 2,2′: 6′,2′′-萜啶，aet = 2-氨基乙硫醇；X = PF6-, n = 2，Solv = CH3CN (1)；X = BF4-, n = 0.5，Solv = H2O (2)；X = -, n = 0 (3)；2X = SiF62-, n = 6，Solv = (4)）是通过[Pd(aet)2]（aet = 2-氨基乙硫醇）与[Pd(NO3)(terpy)]+（terpy = 2,2′: 6′,2′′-萜啶）的反应得到的，使用了不同种类的配对阴离子和溶剂。1—4分子的结构通过X射线晶体学确定，包含两个Pd(terpy)}单元通过一个[Pd(aet)2]单元相连。尽管这些配合物的分子结构相似，但它们之间的分子间结构却有显著不同。1和2呈现单体结构，而3和4则以聚合形式存在。这些结构特征也反映在它们的漫反射光谱中。
• Syntheses, Crystal Structures, and Some Spectrochemical Properties of S-Bridged Tetranuclear Complexes with Stacking Arrangements Composed of Planar Palladium(II) Units
  作者：Yasunori Yamada、Kiyoshi Fujisawa、Ken-ichi Okamoto

  DOI：10.1246/bcsj.73.2067

  日期：2000.9

  The reaction of [Pd(aet)2] (aet = 2-aminoethanethiolate) with [Pd(NO3)2(diimine)] (diimine = 2,2′-bipyridine (bpy), 4,4′-dimethyl-2,2′-bipyridine (dmbpy), 1,10-phenanthroline (phen), 4,7-dimethyl-1,10-phenanthroline (dmphen)) gave a new type of S-bridged tetranuclear complex [Pd(diimine)}2Pd(aet)2}2]4+. The crystal structures of these complexes were determined by X-ray crystallography. In these complexes, the two intramolecular diimine moieties are aligned so as to overlap each other and the PdN2S2 planes in the Pd(aet)2} units are almost perpendicular to those in the Pd(diimine)} moieties. In the case of diimine = bpy and dmbpy, furthermore, the complex cations exist in the dimeric structure with a coplanar stacking arrangement, in which the diimine moieties of the two distinct complex cations are antiparallel to each other. In the case of diimine = phen and dmphen, on the other hand, the complex cations exist in the linear-chain-like structure with an alternate coplanar stacking arrangement, in which the diimine moieties of the neighboring complex cations are antiparallel to each other. All of the complexes were characterized on the basis of the electronic absorption, diffuse reflection, and 13C NMR spectra.

  [Pd(aet)2] (aet = 2-氨基乙硫醇) 与 [Pd(NO3)2(二亚胺)] (二亚胺 = 2,2'-联吡啶 (bpy), 4,4'-二甲基-2, 2′-联吡啶（dmbpy）、1,10-菲咯啉（phen）、4,7-二甲基-1,10-菲咯啉（dmphen））得到了一种新型的S桥四核配合物[Pd(二亚胺)}2 Pd(aet)2}2]4+。这些配合物的晶体结构通过X射线晶体学测定。在这些复合物中，两个分子内二亚胺部分排列成彼此重叠，并且Pd(aet)2}单元中的PdN2S2平面几乎垂直于Pd(二亚胺)}部分中的平面。此外，在二亚胺= bpy和dmbpy的情况下，复合阳离子以共面堆叠排列的二聚结构存在，其中两个不同的复合阳离子的二亚胺部分彼此反平行。另一方面，在二亚胺= phen和dmphen的情况下，络合阳离子以具有交替共面堆叠排列的直链状结构存在，其中相邻络合阳离子的二亚胺部分彼此反平行。所有配合物均根据电子吸收、漫反射和 13C NMR 光谱进行表征。
• The First Ru^IIPd^II₂S₃Metallochelate Ring Formed on a [Ru(bpy)₂]²⁺Core
  作者：Takashi Yoshimura、Atsushi Shinohara、Masakazu Hirotsu、Takumi Konno

  DOI：10.1246/cl.2005.1310

  日期：2005.10

  The 1:2 reaction of [RuCl2(bpy)2] (bpy = 2,2′-bipyridine) with [Pd(aet)2] (aet = 2-aminoethanethiolate) led to the formation of [Ru(bpy)2Pd2(aet)3}Pd(aet)2}]3+ ([1]3+), which was converted into [Ru(bpy)2Pd2(aet)3}Pd(aet)(2-aminoethanesulfenato)}]3+ ([1′]3+) and [Ru(bpy)2Pd2(aet)3Cl}]2+ ([2]2+) having a six-membered RuPd2S3 metallochelate ring.

  1：RuCl2(bpy)2]（bpy = 2,2′-联吡啶）与[Pd(aet)2]（aet = 2-氨基乙硫醇）发生 1：2 反应，生成[Ru(bpy)2Pd2(aet)3}Pd(aet)2}]3+（[1]3+）、转化为具有六元 RuPd2S3 金属螯合环的 [Ru(bpy)2Pd2(aet)3}Pd(aet)(2-aminoethanesulfenato)}]3+ （[1′]3+）和 [Ru(bpy)2Pd2(aet)3Cl}]2+ （[2]2+）。
• Konno, Takumi; Yonenobu, Kunio; Hidaka, Jinsai, Inorganic Chemistry, 1994, vol. 33, # 5, p. 861 - 864
  作者：Konno, Takumi、Yonenobu, Kunio、Hidaka, Jinsai、Okamoto, Ken-Ichi

  DOI：——

  日期：——