| 1147881-01-3

• CAS: 1147881-01-3
• 化学式: C₂₃H₂₉ClNPPd
• 分子量: 492.337
• InChiKey: XHXKJIRIQMZDBW-WUCHBLMUSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 lithium bromide 以 氘代氯仿 为溶剂， 生成
  参考文献：
  名称：

  Reactivity of (3-Iminophosphine)palladium(II) Complexes: Evidence of Hemilability

  摘要：

  Several palladium(II) 3-iminophosphine complexes were synthesized in moderate to high yield. With relevance to many palladium-catalyzed coupling reactions, these complexes incorporate a wide variety of ligands, including amines, alkyls, allyls, and triflates. The presence of both eta'- and eta(2)-coordination modes demonstrates the hemilability of the 3-iminophosphine ligand class, as determined by X-ray crystallography and NMR spectroscopy.

  DOI：

  10.1021/om900066t
• 作为产物：
  描述：

  、 甲基锂 以 四氢呋喃 为溶剂， 以48.2%的产率得到
  参考文献：
  名称：

  Reactivity of (3-Iminophosphine)palladium(II) Complexes: Evidence of Hemilability

  摘要：

  Several palladium(II) 3-iminophosphine complexes were synthesized in moderate to high yield. With relevance to many palladium-catalyzed coupling reactions, these complexes incorporate a wide variety of ligands, including amines, alkyls, allyls, and triflates. The presence of both eta'- and eta(2)-coordination modes demonstrates the hemilability of the 3-iminophosphine ligand class, as determined by X-ray crystallography and NMR spectroscopy.

  DOI：

  10.1021/om900066t