(η(5)-pentamethylcyclopentadienyl)Re(CO)2(N2) | 92787-15-0

• 英文名称: (η(5)-pentamethylcyclopentadienyl)Re(CO)2(N2)
• 英文别名: (η5-C5Me5)Re(CO)2(N2)；Cp*Re(CO)₂N₂；[(η(5)-C5Me5)Re(CO)2N2]
• CAS: 92787-15-0
• 化学式: C₁₂H₁₅N₂O₂Re
• 分子量: 405.47
• InChiKey: BYJBFQICJIKINT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (η(5)-pentamethylcyclopentadienyl)Re(CO)2(N2) 在 氢溴酸 作用下， 以 not given 为溶剂， 生成 cis-[Cp*Re(CO)₂Br₂]
  参考文献：
  名称：

  Barrientos-Penna, Carlos F.; Klahn-Oliva, A. Hugo; Sutton, Derek, Organometallics, 1985, vol. 4, # 2, p. 367 - 373

  摘要：

  DOI：
• 作为产物：
  描述：

  Pentamethylcyclopentadienylrhenium tricarbonyl, min. 98% 在 N₂ 、 O₂ 作用下， 以 四氢呋喃 为溶剂， 生成 (η(5)-pentamethylcyclopentadienyl)Re(CO)2(N2)
  参考文献：
  名称：

  Einstein, Frederick W. B.; Klahn-Oliva, A. Hugo; Sutton, Derek, Organometallics, 1986, vol. 5, # 1, p. 53 - 59

  摘要：

  DOI：

文献信息

• Synthesis, X-ray crystal structure and photochemistry of (η5-pentamethylcyclopentadienyl)(dicarbonyl)(dihydrido) rhenium in cyclohexane and liquid xenon solutions and in low temperature media at about 12 K
  作者：Richard G. Ball、Andrew K. Campen、William A.G. Graham、Paul A. Hamley、Sergei G. Kazarian、Mario A. Ollino、Martyn Poliakoff、Antony J. Rest、Lynda Sturgeoff、Ian Whitwell

  DOI：10.1016/s0020-1693(97)05443-1

  日期：1997.6

  primary photoproduct is the cis isomer and that trans to cis interconversion, which can be reversed thermally, is an intramolecular process. Photochemical studies of (η5-C5Me5)Re-(CO)2N2) in liquid Xe under H2 and D2 pressures at 200 K gave cis-(η5-C5Me5)Re(CO)2 and cis-(η5-C5Me5)Re(CO)2(D)2, respectively. Matrix isolation studies at about 12 K, including 13CO labelling, confirmed that the photoisomerisation

  的改进的合成（η 5 -C 5我5）的Re（CO）2（H）2通过已经设计出（产率88％）（η 5 -C 5我5）重新CO）3和（η 5 -C 5 Me 5）-Re（CO）2（Br）2。X射线晶体学测定表明，经IR和NMR测量证实，氢化物配体占据了反式位置。的性质和反应反式- （η 5 -C 5我5）的Re（CO）2（H）2和相关化合物（η 5 -C 5我5）重（CO）2（X）（Y）（XH，我; YH，Me中，Cl）的被描述。的溶液photoctemistry反式- （η 5 -C 5我5）重新CO 2（H）2）在在298K和在200K的液体氙环己烷，包括d下研究2，指示主要光化产物是顺式异构体，可以热逆转的反式到顺式互变分子内过程。（光化学研究η 5 -C 5我5）重（CO）2 Ñ 2在液体下的Xe 1H）2和d 2个在200K的压力，得到顺式- （η 5 -C 5我5）的Re（CO）2及顺式-
• Reactions of the rhenium fragment (η5-C5Me5)Re(CO)2 with chlorinated ethylenes: Coordination and C–Cl bond activation
  作者：Rodrigo Arancibia、Fernando Godoy、María Teresa Garland、Andrés Ibáñez、Ricardo Baggio、A. Hugo Klahn

  DOI：10.1016/j.jorganchem.2006.10.050

  日期：2007.2

  Photochemical reactions of the dinitrogen complex Cp∗Re(CO)2N2 with tetrachloroethylene and trichloroethylene yield the coordination complexes Cp∗Re(CO)2(η2-tetrachloroethylene) (1) and Cp∗Re(CO)2(η2-trichloroethylene) (2), respectively. Complex 1 reacts thermally in polar organic solvents to produce the C–Cl bond activation product cis-Cp∗Re(CO)2(C2Cl3)Cl (3). All complexes were isolated and characterized

  一氧化二复杂Cp的光化学反应*的Re（CO）2 Ñ 2与四氯乙烯和三氯乙烯得到的配位络合物的Cp *的Re（CO）2（η 2 -tetrachloroethylene）（1）1和Cp *的Re（CO）2（η 2 -三氯乙烯）（2）。络合物1在极性有机溶剂中发生热反应，生成C–Cl键活化产物顺式-Cp ∗ Re（CO）2（C 2 Cl 3）Cl（3）。分离所有复合物，并通过IR，1 H和13 C NMR光谱法和质谱进行表征。配合物3也通过X射线晶体学表征。
• Klahn, A. Hugo; Sutton, Derek, Organometallics, 1989, vol. 8, # 1, p. 198 - 206
  作者：Klahn, A. Hugo、Sutton, Derek

  DOI：——

  日期：——
• Klahn-Oliva, Hugo A.; Singer, Robert D.; Aramini, James M., Inorganic Chemistry, 1989, vol. 28, # 23, p. 4217 - 4221
  作者：Klahn-Oliva, Hugo A.、Singer, Robert D.、Aramini, James M.、Sutton, Derek

  DOI：——

  日期：——
• η²-COORDINATION OF CHLOROBENZENES TO RHENIUM FRAGMENT Cp*Re(CO)2: CHEMICAL AND PHOTOCHEMICAL SYNTHESES OF Cp*Re(CO)2(η²-C6H6-nCl n)
  作者：A. HUGO KLAHN、VERÓNICA MORALES、BEATRIZ OELCKERS、GONZALO E BUONO-CORE、JOHAND GOMEZ、FERNANDO GODOY

  DOI：10.4067/s0717-97072011000300022

  日期：——

  The complexes Cp*Re(CO)(2)(eta(2)-C6H6-nCln), n = 4, (5,6-eta(2)-1,2,3,4-C6H2Cl4) 2a; n = 3, (5,6-eta(2)-1,2,4-C6H3Cl3) 2b; n = 2, (2,3-eta(2)-1,4-C6H3Cl2) 2c and (4,5-eta(2)-1,3-C6H3Cl2) 2d, have been conveniently prepared by two alternative procedures: Directly, by the photochemical reaction of Cp*Re(CO)(2)(N-2) in neat or saturated hexane solution of the corresponding partially chlorinated benzene or stepwise, by the reaction of the appropriate trans-Cp*Re(CO)(2)(Ar-cl)X, X = Cl, Br (1a-d) with LiBHEt3 followed by protonation with HCl to form the hydrido complexes trans-Cp*Re(CO)(2)(Ar-ct)H which resulted thermally unstable in solution and convert to eta(2)-coordination complexes 2a-d. Due to their low stability as solids and in solution, the new complexes were only characterized by IR and H-1 and C-13 NMR spectroscopy. The H-1 NMR spectra of the two derivatives containing dichlorobenzene (2c and 2d) indicate that a rapid exchange occurs between the hydrogen atoms on the coordinated carbons and those on the non-coordinated carbons.