Pt3(μ2-CO)3(benzyldiphenylphosphine)3 | 15683-57-5

• 英文名称: Pt3(μ2-CO)3(benzyldiphenylphosphine)3
• 英文别名: [Pt3(μ-CO)3(PBzPh2)3]；[Pt3(μ-CO)3(PPh2Bz)3]；[Pt3(μ-CO)(PBzPh2)3]
• CAS: 15683-57-5
• 化学式: C₆₀H₅₁O₃P₃Pt₃
• 分子量: 1498.22
• InChiKey: BMKCUZJCCNTTKT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  Pt3(μ2-CO)3(benzyldiphenylphosphine)3 、 六氟-2-丁炔 以 二氯甲烷 为溶剂， 以44%的产率得到[Pt2(CO)2(PPh2Bz)2(μ-η1:η1-CF3C2CF3)2]
  参考文献：
  名称：

  三角簇[Pt 3（μ-CO）3（PR 3）3 ]与六氟丁炔的反应。的X射线晶体结构[PT 2（CO）2（PR 3）2（μ-η 2：η 2 -CF 3 CCCF 3）]（PR 3 = PPH 3或PCY 3）和[PT 2（CO ）2（PBzPh 2）（μ-η 1：η 1 -CF 3 CCCF 3）2 ]

  摘要：

  六氟-2-丁炔，CF 3 Ç CCF 3，与发生反应triangulo -clusters [PT 3（μ-CO）3（PR 3）3 ]，得到二铂（0）的化合物[铂2（CO）2（PR 3）2（μ -η 2：η 2 -CF 3 ç CCF 3）] {PR 3 = PPH 3（1），PBzPh 2（2），PCY 3（3），P我镨3（4）}。据报道，其光谱性质与1和3的分子结构一致，两者的炔属C–C轴均垂直于Pt–Pt轴，将两个[Pt（CO）（PR 3）]片段桥接成μ- η 2：η 2时尚。大大过量六氟丁炔慢慢地转换1和2的二铂（II）配合物[PT 2（CO）2（PR 3）2（μ-η 1：η 1 -CF 3 Ç CCF 3）2 ] {PR 3 = PPH 3（5） ，PBzPh 2（6）}，具有两个平面六氟丁炔桥梁。这种立体化学是由核磁共振 和 红外光谱，并通过单晶X射线衍射确认。

  DOI：

  10.1039/b203075f
• 作为产物：
  描述：

  PtCl2(1,5-cyclooctadiene) 、 一氧化碳 、 苄基二苯膦 在 氢氧化钾 、 双氧水 作用下， 以 四氢呋喃 、 乙醇 、 水 为溶剂， 以63%的产率得到Pt3(μ2-CO)3(benzyldiphenylphosphine)3
  参考文献：
  名称：

  Synthesis and 13C NMR study of the triangulo-clusters [Pt3(μ-CO)3−n(μ-SO2)n(PR3)3] (n=0–3)

  摘要：

  [Pt-3(mu-CO)(3)(PPh3)(3)] was prepared in high yield by the reaction of [Pt-3(mu-CO)(3)(PPh3)(4)] with H2O2. The carbonyl ligands in [Pt-3(mu-CO)(3)(PR3)(3)] (PR3 = PPh3, PPh(2)Bz, PCy3, P'Pr-3) may be completely replaced by sulfur dioxide to give [Pt-3(mu-SO2)(3)(PR3)(3)] or partially by one SO2 to give [Pt-3(mu-CO)(2)(mu-SO2)(PR3)(3)] (PR3 = PCy3 and (PPr3)-Pr-i). On the other hand, the addition of one molar equivalent of carbon monoxide to [Pt-3(mu-SO2)(3)(PR3)(3)] (PR3 = PCy3, (PPr3)-Pr-i) gave the complexes [Pt-3(mu-CO)(mu-SO2)(2)(PR3)(3)] Complete simulation of the C-13 NMR spectra could be achieved with the help of Pt-195 NMR data. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00523-x

文献信息

• The reaction of alkynes with triangulo-clusters [Pt3(µ-CO)3(PR3)3]
  作者：Renzo Ros、Augusto Tassan、Raymond Roulet、Virginie Duprez、Serena Detti、Gàbor Laurenczy、Kurt Schenk

  DOI：10.1039/b103306a

  日期：——

  The reaction of the cluster complexes [Pt3(μ-CO)3(PR3)3] (PR3 = PPh3  1, PPh2Bz  2, PCy3  3 and PiPr3  4) with dialkyl acetylenedicarboxylate, R′O2CCCCO2R′ (R′ = CH3 or tBu) have been examined under various conditions. At low temperature the alkyne reacts quantitatively giving the unstable adducts [Pt3(CO)3(PR3)3(μ3-alkyne)]. The stereochemistry of the intermediate [Pt3(CO)3(PPh3)3(μ3-tBuO2CCCCO2tBu)] 5 has been deduced from low temperature 195Pt-1H}, 31P-1H} and 13C-1H} NMR spectra. At higher temperature a fluxional process renders two of the three platinum atoms equivalent on the NMR timescale. At room temperature the alkynes convert the starting clusters 1–4 to the stable dinuclear complexes [Pt2(CO)2(PR3)2(μ-R′O2CCCCO2R′)] (R′ = CH3, PR3 = PPh3  6; R = tBu, PR3 = PPh3  7; PPh2Bz  8; PCy3  9 and PiPr3  10) in which the alkyne coordination has the C–C bond collinear with the Pt–Pt bond (6 and 7) or perpendicular to the Pt–Pt axis (9 and 10). The stereochemistry of these two types of dinuclear complexes has been established by NMR and IR studies and confirmed by X-ray diffraction analyses of 8 and 9.

  簇配合物的反应 [Pt3(μ-CO)3(PR3)3] (PR3=PPh3 1、PPh2Bz 2、PCy3 3 和 PiPr3 4) 与乙炔二甲酸二烷基酯一起，在各种条件下对 R−O2CCCCO2R−（R−= CH3 或 tBu）进行了研究。在低温下，炔烃定量反应，生成不稳定的加合物 [Pt3(CO)3(PR3)3(μ3-炔烃)]。中间体的立体化学 [Pt3(CO)3(PPh3)3(μ3-tBuO2CCCCO2tBu)] 5 由低温 195Pt-1H}、31P-1H} 和 13C-1H} NMR 谱推导出来。在较高温度下，流变过程使得三个铂原子中的两个在核磁共振时间尺度上等效。在室温下，炔烃将起始簇 1–4 转化为稳定的双核配合物 [Pt2(CO)2(PR3)2(μ-R–O2CCCCO2R–2)] (R–2= , PR3=PPh3 6； R=tBu, PR3=PPh3 7； PPh2Bz 8; PCy3 9 和 PiPr3 10) 其中炔配位的 C–C 键与 Pt–Pt 键共线（6 和 7）或垂直于 Pt–Pt 轴（9 和 10）。这两种双核配合物的立体化学已通过 NMR 和 IR 研究确定，并通过 8 和 9 的 X 射线衍射分析得到证实。
• Synthesis of some pentanuclear platinum clusters [Pt5(CO)6(L)4]. The X-ray structure of [Pt5(μ-CO)5(CO)(PCy3)4]
  作者：Zoltàn Béni、Renzo Ros、Augusto Tassan、Rosario Scopelliti、Raymond Roulet

  DOI：10.1016/j.ica.2004.06.056

  日期：2005.2

  [Pt-5(mu-CO)(5)(CO)L-4] (L = PPh3 1, PPh(2)Bz 2, AsPh3 3, PEt3 4, PCy3 5) have been synthesized by reacting [Pt-3(mu-CO)(3)(PR3)(3)] with H2O2 (1 and 2), by reduction of cis-[PtCl2(CO)(PEt3)] with Zn dust (4), and by the Zn reduction of [Pt-3(mu-CO)(3)(PCy3)(3)] in the presence of [PtCl2(CH3CN)(2)] (5). Complex 5 has not been observed previously and has been characterized by X-ray crystallography. Oxidation of the phosphine ligands with H2O2 is a new way to synthesize 1 and 2. The first complete NMR characterization of these complexes has also been achieved. and showed that these pentanuclear cluster complexes exhibit similar stereochemistries in solution and in the solid state. The observed (1)J(Pt) (Pt) values do not have any correlation with the corresponding bond lengths, again pointing out the irregular behaviour of such parameter in Pt complexes. (C) 2004 Elsevier B.V. All rights reserved.
• 31P and 195Pt nmr studies on the triangular cluster complexes [Pt3(μ-CO)3(tertiary phosphine)4]
  作者：Alfred Moor、Paul S Pregosin、Luigi M Venanzi

  DOI：10.1016/s0020-1693(00)89131-8

  日期：1982.1