Tetraborane(4), tetrachloro- | 17156-85-3

• 英文名称: Tetraborane(4), tetrachloro-
• 英文别名: tetraboron tetrachloride
• CAS: 17156-85-3
• 化学式: B₄Cl₄
• 分子量: 185.056
• InChiKey: YOHWXMLUCAWFPM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Tetraborane(4), tetrachloro- 、 三甲基锡 以 further solvent(s) 为溶剂， 以95%的产率得到tetraborane
  参考文献：
  名称：

  Emery; Morrison, Inorganic Chemistry, 1985, vol. 24, # 11, p. 1612 - 1613

  摘要：

  DOI：
• 作为产物：
  描述：

  三氯化硼 在 汞 作用下， 以 gas 为溶剂， 生成 Tetraborane(4), tetrachloro- 、 1,1,2,2-四氯-二硼烷
  参考文献：
  名称：

  Possible intermediates in the discharge synthesis of diboron tetrahalides

  摘要：

  DOI：

  10.1016/s0277-5387(00)88124-3

文献信息

• Tetrakis(t-butyl)tetraborane(4), Bu4 tB4; synthesis of the first peralkyl derivative of a 2N framework electron count deltahedral borane
  作者：T. Davan、J. A. Morrison

  DOI：10.1039/c39810000250

  日期：——

  The reaction of B4Cl4with lithium alkyls results in the formation of alkylated and peralkylated derivatives of the tetraboron framework; the examples reported include EtB4Cl3, Et2B4Cl2, and Bu4tB4.

  B 4 Cl 4与烷基锂的反应导致四硼骨架的烷基化和全烷基化衍生物的形成；报道的例子包括EtB 4 Cl 3，Et 2 B 4 Cl 2和Bu 4 t B 4。
• Saulys; Castillo; Morrison, Inorganic Chemistry, 1989, vol. 28, # 9, p. 1619 - 1624
  作者：Saulys、Castillo、Morrison

  DOI：——

  日期：——
• Chemistry of tetraboron tetrachloride. Synthesis and characterization of tetraboron tetrabromide (B4Br4) and observation of B4BrCl3, B4Br2Cl2, and B4Br3Cl
  作者：L. Ahmed、J. Castillo、J. A. Morrison

  DOI：10.1021/ic00036a025

  日期：1992.5

  In the absence of added solvent, B4Cl4 and BBr3, present in a 1:5 mole ratio, generated B4BrCl3 in approximately 13% yield after 800 h at 95-degrees-C. Repeated exposure of B4Cl4 to fresh aliquots of BBr3 and pentane at 95-degrees-C did ultimately (2200 h) form B4Br4 and the mixed ligand species B4Br3Cl, B4Br2Cl2, and B4BrCl3, but the quantities provided were small. The boron-11 NMR data for the bromochlorotetraboranes are consistent with a tetrahedral configuration of the boron atoms rather than a square-planar-based array. In thc presence of AlBr3, B4Br4 was generated from the interaction of B4Cl4 with BBr3 at 95-degrees-C and isolated in 80% yield. After 144 h at 110-degrees-C, the reaction of B4Br4 with excess BCl3 regenerated B4Cl4 in ca. 90% yield.