niobium(II) sulfide

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属有机体
• 英文名称: niobium(II) sulfide
• 英文别名: niobium monosulfide；niobium;sulfane
• 化学式: NbS
• 分子量: 124.972
• InChiKey: ROEPXOSJXFTHON-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.11
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  niobium(II) sulfide 在 O₂ 作用下， 以 neat (no solvent) 为溶剂， 生成 niobium(V) oxide
  参考文献：
  名称：

  Oganesyan, V. Kh.; Bukhanevich, V. F.; Radzikovskaya, S. V., 1966, vol. 19, p. 161 - 166

  摘要：

  DOI：
• 作为产物：
  描述：

  niobium sulfide 以 neat (no solvent) 为溶剂， 生成 niobium(II) sulfide
  参考文献：
  名称：

  Vrinat, M.; Guillard, C.; Lacroix, M., Bulletin des Societes Chimiques Belges, 1987, vol. 96, # 11-12, p. 1017 - 1025

  摘要：

  DOI：

文献信息

• MnNbS/Polyaniline Composite‐Based Electrode Material for High‐Performance Energy Storage Hybrid Supercapacitor Device
  作者：Rizwan Khan、Amir Muhammad Afzal、Zahid Hussain、Muhammad Waqas Iqbal、Muhammad Imran、Muhammad Hamza Waris、Muhammad Azhar Mumtaz、Muhammad Usman、Saikh Mohammad Wabaidur、Essam A. Al-Ammar、Sohail Mumtaz

  DOI：10.1002/pssa.202300200

  日期：2023.8

  Hybrid supercapacitor or supercapattery devices have gained significant attention for their impressive power (P_d) and energy densities (E_d), as well as their exceptional cyclic stability compared to traditional storage devices. In this study, manganese niobium sulfide (MnNbS) is synthesized using a hydrothermal method. To enhance the electrochemical performance of MnNbS, polyaniline (PANI) is blended at varying mass ratios. Initially, the electrochemical properties of MnNbS/PANI are evaluated using a three‐electrode configuration, consisting of working, counter, and reference electrodes. At a current density of 2 A g⁻¹, MnNbS/PANI exhibits an improved specific capacity () of 1366 C g⁻¹. Subsequently, to develop a supercapattery energy storage device, a two‐electrode system is constructed. This setup offers enhanced performance and flexibility, making it an ideal choice for high‐performance supercapacitors. Activated carbon (AC) and MnNbS/PANI are employed as the negative and positive electrodes, respectively, in the two‐electrode system. Notably, the device demonstrates outstanding energy density (E_d) of 26.2 Wh kg⁻¹, power density (P_d) of 2072 W kg⁻¹, and specific capacity of 118 C g⁻¹. Furthermore, durability tests involving 1000 charge–discharge cycles reveal a capacity retention of 79%. This study suggests that MnNbS/PANI (at a weight ratio of 80/20%) holds promise as an electrode material for supercapattery applications.

  混合超级电容器或超级电池装置因其令人印象深刻的功率密度（Pd）和能量密度（Ed），以及与传统存储装置相比卓越的循环稳定性而备受关注。本研究采用水热法合成了硫化锰铌（MnNbS）。为了提高 MnNbS 的电化学性能，以不同的质量比掺入了聚苯胺（PANI）。最初，我们使用由工作电极、对电极和参比电极组成的三电极配置来评估 MnNbS/PANI 的电化学性能。在电流密度为 2 A g-1 时，MnNbS/PANI 的比容量（）提高到 1366 C g-1。随后，为了开发超级电池储能装置，我们构建了一个双电极系统。这种装置具有更高的性能和灵活性，是高性能超级电容器的理想选择。在双电极系统中，活性炭（AC）和 MnNbS/PANI 分别用作负极和正极。值得注意的是，该装置的能量密度（Ed）达到 26.2 Wh kg-1，功率密度（Pd）达到 2072 W kg-1，比容量达到 118 C g-1。此外，1000 次充放电循环的耐久性测试显示，容量保持率为 79%。这项研究表明，MnNbS/PANI（重量比为 80/20%）有望成为超级电池应用的电极材料。
• On the magnetic behavior of new 2HNbS2-type derivatives
  作者：Fritz Hulliger、Eva Pobitschka

  DOI：10.1016/0022-4596(70)90001-0

  日期：1970.1

  The magnetic behavior of compounds of the type TxNbS2 with and was studied below room temperature. No magnetic order was found with T = Ti and V, whereas with Cr the phases with become ferromagnetic.

  的类型T的化合物的磁性行为X NBS 2与和低于室温进行了研究。T = Ti和V时未发现磁性，而Cr时则为铁磁性。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Nb: MVol.A, 6.1, page 289 - 305
  作者：

  DOI：——

  日期：——
• Ba₃TM₂Se₉ (TM = Nb, Ta): Synthesis and Characterization of New Polyselenides
  作者：Ming-Yan Chung、Chi-Shen Lee

  DOI：10.1021/ic4013763

  日期：2014.1.6

  New ternary polyselenides Ba3TM2Se9 (TM = Nb, Ta) were synthesized through a solid-state reaction, and their structures were characterized using single-crystal X-ray diffraction. These compounds crystallized into a new structural type with a monoclinic space group P2(1)/c. The structures were constructed from distorted, close-packed layers of (3)(infinity)[BaSe3](3.33-) that incorporated TM atoms at octahedral sites and contained [(TM5+)(2)(Se2-)(7)(Se-2(2-))] units. Diffuse reflectance spectra and electronic resistivity measurements indicated semiconducting properties and optical band gaps of 1.3 eV for Ba3Nb2Se9 and 1.6 eV for Ba3Ta2Se9. Raman spectra were used to investigate the interatomic interactions. Calculations of the electronic structure verified the semiconducting behavior and bonding interaction of short Se-Se contacts.
• Synthesis and characterization of ternary layered Nb2SB ceramics fabricated by spark plasma sintering
  作者：Yanru Qin、Yanchun Zhou、Longfeng Fan、Qingguo Feng、Salvatore Grasso、Chunfeng Hu

  DOI：10.1016/j.jallcom.2021.160344

  日期：2021.10