Copper;thorium | 11091-81-9

• 分子结构分类: 无机化合物 - 均相金属化合物 - 金属间过渡金属化合物
• 英文名称: Copper;thorium
• CAS: 11091-81-9
• 化学式: Cu₂Th
• 分子量: 359.13
• InChiKey: KQDYOGHAGNJBRA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Copper;thorium 在 air 作用下， 生成
  参考文献：
  名称：

  Partial oxidation of methane over bimetallic copper- and nickel-actinide oxides (Th, U)

  摘要：

  The study of partial oxidation of methane (POM) over bimetallic nickel- or copper-actinide oxides was undertaken. Binary intermetallic compounds of the type AnNi(2) (An = Th, U) and ThCu2 were used as precursors and the products (2NiO UO3, 2NiO ThO2 and 2CuO ThO2) characterized by means of Xray diffraction, X-ray photoelectron spectroscopy, Raman spectroscopy and temperature-programmed reduction. The catalysts were active and selective for the conversion of methane to H-2 and CO and stable for a period of time of approximate to 18 h on stream. The nickel catalysts were more active and selective than the copper catalyst and, under the same conditions, show a catalytic behaviour comparable to that of a platinum commercial catalyst, 5 wt% Pt/Al2O3 The catalytic activity increases when uranium replaces thorium and the selectivity of this type of materials is clearly different from that of single metal oxides and/or mechanical mixtures. The good catalytic behaviour of the bimetallic copper- and nickel-actinide oxides was attributed to an unusual interaction between copper or nickel oxide and the actinide oxide phase as showed by H-2-TPR, XPS and Raman analysis of the catalysts before and after reaction. (C) 2010 Elsevier B V. All rights reserved.

  DOI：

  10.1016/j.jallcom.2010.03.021

文献信息

• Actinide heterobimetallic oxides (Th, U): reduction studies
  作者：Joaquim Branco、Catarina de Jesus Dias、António Pereira Gonçalves、Teresa Almeida Gasche、António Pires de Matos

  DOI：10.1016/j.tca.2003.11.060

  日期：2004.10
• Partial oxidation of methane over bimetallic copper- and nickel-actinide oxides (Th, U)
  作者：Ana C. Ferreira、A.P. Gonçalves、T. Almeida Gasche、A.M. Ferraria、A.M. Botelho do Rego、M.R. Correia、A. Margarida Bola、J.B. Branco

  DOI：10.1016/j.jallcom.2010.03.021

  日期：2010.5

  The study of partial oxidation of methane (POM) over bimetallic nickel- or copper-actinide oxides was undertaken. Binary intermetallic compounds of the type AnNi(2) (An = Th, U) and ThCu2 were used as precursors and the products (2NiO UO3, 2NiO ThO2 and 2CuO ThO2) characterized by means of Xray diffraction, X-ray photoelectron spectroscopy, Raman spectroscopy and temperature-programmed reduction. The catalysts were active and selective for the conversion of methane to H-2 and CO and stable for a period of time of approximate to 18 h on stream. The nickel catalysts were more active and selective than the copper catalyst and, under the same conditions, show a catalytic behaviour comparable to that of a platinum commercial catalyst, 5 wt% Pt/Al2O3 The catalytic activity increases when uranium replaces thorium and the selectivity of this type of materials is clearly different from that of single metal oxides and/or mechanical mixtures. The good catalytic behaviour of the bimetallic copper- and nickel-actinide oxides was attributed to an unusual interaction between copper or nickel oxide and the actinide oxide phase as showed by H-2-TPR, XPS and Raman analysis of the catalysts before and after reaction. (C) 2010 Elsevier B V. All rights reserved.