Palladium--praseodymium (3/1) | 12165-84-3

• 分子结构分类: 无机化合物 - 均相金属化合物 - 金属间过渡金属化合物
• 英文名称: Palladium--praseodymium (3/1)
• 英文别名: palladium;praseodymium
• CAS: 12165-84-3
• 化学式: Pd₃Pr
• 分子量: 460.168
• InChiKey: YYCCQOOWUNQNMW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Palladium--praseodymium (3/1) 、 sulfur 以 neat (no solvent, solid phase) 为溶剂， 生成
  参考文献：
  名称：

  A New Multipolar Ordering Compound, Rare-Earth Palladium Bronze PrPd₃S₄

  摘要：

  Specific heat and magnetization measurements were performed on single crystalline PrPd3S4. A lambda-type anomaly at T-M = 1.56 K in the specific heat shifts to higher temperatures by magnetic fields, begins to shift to lower temperatures above 2T, and disappears above 3.6T. The 4f ground state of Pr3+ was deduced to be a magnetic triplet. Below T-M, the magnetic susceptibility increases while no spontaneous magnetization appears. These results strongly reveal that PrPd3S4 shows a multipolar ordering at T-M. The most probable ordering state for PrPd3S4 is an antiferroquadrupolar (AFQ) ordering since the B-T phase diagrams are of the "re-entrant" type, which is typical for AFQ ordering compounds.

  DOI：

  10.1143/jpsj.76.073707
• 作为产物：
  描述：

  三氢化镨 、 钯 以 neat (no solvent) 为溶剂， 生成 Palladium--praseodymium (3/1)
  参考文献：
  名称：

  Kucherenko, Yu.; Finken, M.; Molodtsov, S. L., Physical Review B: Condensed Matter and Materials Physics, p. 1 - 4

  摘要：

  DOI：

文献信息

• Kucherenko, Yu.; Finken, M.; Molodtsov, S. L., Physical Review B: Condensed Matter and Materials Physics, p. 1 - 4
  作者：Kucherenko, Yu.、Finken, M.、Molodtsov, S. L.、Heber, M.、Boysen, J.、et al.

  DOI：——

  日期：——
• A New Multipolar Ordering Compound, Rare-Earth Palladium Bronze PrPd₃S₄
  作者：Eiichi Matsuoka、Daichi Usui、Hiroshi Tanida、Shintaro Nakamura、Tsutomu Nojima、Hideya Onodera

  DOI：10.1143/jpsj.76.073707

  日期：2007.7.15

  Specific heat and magnetization measurements were performed on single crystalline PrPd3S4. A lambda-type anomaly at T-M = 1.56 K in the specific heat shifts to higher temperatures by magnetic fields, begins to shift to lower temperatures above 2T, and disappears above 3.6T. The 4f ground state of Pr3+ was deduced to be a magnetic triplet. Below T-M, the magnetic susceptibility increases while no spontaneous magnetization appears. These results strongly reveal that PrPd3S4 shows a multipolar ordering at T-M. The most probable ordering state for PrPd3S4 is an antiferroquadrupolar (AFQ) ordering since the B-T phase diagrams are of the "re-entrant" type, which is typical for AFQ ordering compounds.