| 289057-84-7

• CAS: 289057-84-7
• 化学式: C₃₆H₄₄ClP₂Ru*F₆P
• 分子量: 820.18
• InChiKey: HESPMFBTAWXIKV-LDBDCIKGSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  sodium hexaflorophosphate 、 [(η6-C6Me6)RuCl2(DMPP)] 、 1-苯基-3,4-二甲基膦杂环戊二烯) 以 1,2-二氯乙烷 为溶剂， 以28%的产率得到
  参考文献：
  名称：

  Thermal Dimerization of 3,4-Dimethyl-1-Phenylphosphole within the Coordination Sphere of [(η⁶-Arene)Ru(DMPP)₂Cl]PF₆ Complexes

  摘要：

  Thermolysis of a 1,2-dichlaroethane solution containing a 1:1.5:1 molar ratio of (eta(6)-C-6-Me-6)Ru(DMPP)Cl-2, DMPP, and NaPF6 produced [(eta(6)-C6Me6)Ru(DMPP)(2)Cl]PF6 (1), [(eta(6)-C-6-Me-6)Ru(DMPP)(2)[4+4]Cl]PF6 containing an unprecedented [4+4] DMPP cyclodimer (2), [(eta(6)-C6Me6)Ru(DMPP)(2)[4+2]CI]PF6 containing a [4+2] Diels-Alder dimer of DMPP (3), and (eta(6)- C6Me6)Ru(3-methyl-4-methylene-1-phenyl-2-phospholene)Cl-2 (4) that results from an allylic [1,3]-hydrogen shift. Thermolysis of a 1,2-dichloroethane solution containing a 1:1.5:1 molar ratio of (eta(6)-p-MeC6H4CHMe2)Ru(DMPP)Cl-2, DMPP, and NaPF6 produced [p(eta(6)-p-MeC6H4-CHMe2)Ru(mu-Cl)(3)Ru(DMPP)(2)[4+2](DMPP)]PF6 (5), containing a Diels-Alder [4+2] DMPP dimer, and [(DMPP)(3)Ru(mu-Cl)(3)Ru(DMPP)(3)]PF6 (6), All these complexes have been characterized by elemental analyses, physical properties, infrared spectroscopy, cyclic voltammetry, X-ray crystallography, and H-1, H-1{(31)p}, C-13{H-1}, and P-31{H-1} NMR spectroscopy.

  DOI：

  10.1021/om000300p