[(2-(2,4-difluorophenyl)-6-fluoro-1,3-benzothiazolato-N,C(2'))2IrCl]2 | 838845-59-3

• 英文名称: [(2-(2,4-difluorophenyl)-6-fluoro-1,3-benzothiazolato-N,C(2'))2IrCl]2
• CAS: 838845-59-3
• 化学式: C₅₂H₂₀Cl₂F₁₂Ir₂N₄S₄
• 分子量: 1512.35
• InChiKey: QEWSPMYWEDXOKD-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [(2-(2,4-difluorophenyl)-6-fluoro-1,3-benzothiazolato-N,C(2'))2IrCl]2 、 乙酰丙酮 在 sodium carbonate 作用下， 以 乙二醇乙醚 为溶剂， 以58%的产率得到iridium(III)bis[2-(2,4-difluorophenyl)-6-fluoro-1,3-benzothiazolato-N,C(2')]-acetylacetonate
  参考文献：
  名称：

  Color tunable phosphorescent light-emitting diodes based on iridium complexes with substituted 2-phenylbenzothiozoles as the cyclometalated ligands

  摘要：

  Several iridium complexes {iridium(III)bis[2-(3-methoxyphenyl)- 1,3-benzothiozolato-N,C-2'] acetylacetonate (MeO-BT)(2)Ir(acac), iridium(III)bis[2-(2,4-difluorophenyl)-1,3-benzothiozolato-N,C-2'] acetylacetonate (2F-BT)(2)Ir(acac), and iridium(III)bis[2-(2,4-difluorophenyl)-6-fluoro-1,3-benzothiozolato-N, C-2'] acetylacetonate (3F-BT)(2)Ir(acac)} having different substituents on 2-phenyl-benzothiazole have been synthesized. The phosphorescent light emitting diodes (PHOLEDs) using these iridium complexes as dopant emitters were fabricated. The,experimental results revealed that the emissive colors of PHOLEDs could be finely tuned by suitable modification of the substituents on the 2-phenylbenzothiazole ligands. Furthermore, these iridium Complexes show better emissive properties than the known iridium(III)bis(2-phenylbenzothiozolato-N,C-2') acetylacetonate (BT)(2)Ir(acac). (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.07.003
• 作为产物：
  描述：

  氯化铱(III) 水合物 、 2-(2,4-Difluorophenyl)-6-fluoro-1,3-benzothiazole 以 乙二醇甲醚 、 水 为溶剂， 生成 [(2-(2,4-difluorophenyl)-6-fluoro-1,3-benzothiazolato-N,C(2'))2IrCl]2
  参考文献：
  名称：

  Color tunable phosphorescent light-emitting diodes based on iridium complexes with substituted 2-phenylbenzothiozoles as the cyclometalated ligands

  摘要：

  Several iridium complexes {iridium(III)bis[2-(3-methoxyphenyl)- 1,3-benzothiozolato-N,C-2'] acetylacetonate (MeO-BT)(2)Ir(acac), iridium(III)bis[2-(2,4-difluorophenyl)-1,3-benzothiozolato-N,C-2'] acetylacetonate (2F-BT)(2)Ir(acac), and iridium(III)bis[2-(2,4-difluorophenyl)-6-fluoro-1,3-benzothiozolato-N, C-2'] acetylacetonate (3F-BT)(2)Ir(acac)} having different substituents on 2-phenyl-benzothiazole have been synthesized. The phosphorescent light emitting diodes (PHOLEDs) using these iridium complexes as dopant emitters were fabricated. The,experimental results revealed that the emissive colors of PHOLEDs could be finely tuned by suitable modification of the substituents on the 2-phenylbenzothiazole ligands. Furthermore, these iridium Complexes show better emissive properties than the known iridium(III)bis(2-phenylbenzothiozolato-N,C-2') acetylacetonate (BT)(2)Ir(acac). (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.07.003