5,5-difluoro-10-(4'-formyl-[1,1'-biphenyl]-4-yl)-1,9-dimethyl-3,7-distyryl-5H-5l4-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium | 1375477-17-0

• 英文名称: 5,5-difluoro-10-(4'-formyl-[1,1'-biphenyl]-4-yl)-1,9-dimethyl-3,7-distyryl-5H-5l4-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium
• CAS: 1375477-17-0
• 化学式: C₄₀H₃₁BF₂N₂O
• 分子量: 604.507
• InChiKey: DLSWCWKJDLKYGE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  肌氨酸 、 5,5-difluoro-10-(4'-formyl-[1,1'-biphenyl]-4-yl)-1,9-dimethyl-3,7-distyryl-5H-5l4-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium 、 足球烯 以 甲苯 为溶剂， 反应 12.0h， 以60%的产率得到
  参考文献：
  名称：

  Styryl Bodipy-C₆₀ Dyads as Efficient Heavy-Atom-Free Organic Triplet Photosensitizers

  摘要：

  C-60-styryl Bodipy dyads that show strong absorption of visible light (epsilon = 64 600 M-1 cm(-1) at 657 nm) and a long-lived triplet excited state (tau(T)=123.2 mu s) are prepared. The dyads were used as heavy-atom-free organic triplet photosensitizers for photooxidation of 1,5-dihydroxynaphthalene via the photosensitizing of singlet oxygen (O-1(2)). The photooxidation efficiency of the dyads compared to the conventional Ir(III) complex O-1(2) photosensitizer increased 19-fold.

  DOI：

  10.1021/ol3008843
• 作为产物：
  描述：

  10-(4-bromophenyl)-5,5-difluoro-1,9-dimethyl-3,7-distyryl-5H-5l4-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium 、 4-甲酰基苯硼酸 在 四(三苯基膦)钯 、 potassium carbonate 作用下， 以 乙醇 、 水 、 甲苯 为溶剂， 反应 8.0h， 以85%的产率得到5,5-difluoro-10-(4'-formyl-[1,1'-biphenyl]-4-yl)-1,9-dimethyl-3,7-distyryl-5H-5l4-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium
  参考文献：
  名称：

  Styryl Bodipy-C₆₀ Dyads as Efficient Heavy-Atom-Free Organic Triplet Photosensitizers

  摘要：

  C-60-styryl Bodipy dyads that show strong absorption of visible light (epsilon = 64 600 M-1 cm(-1) at 657 nm) and a long-lived triplet excited state (tau(T)=123.2 mu s) are prepared. The dyads were used as heavy-atom-free organic triplet photosensitizers for photooxidation of 1,5-dihydroxynaphthalene via the photosensitizing of singlet oxygen (O-1(2)). The photooxidation efficiency of the dyads compared to the conventional Ir(III) complex O-1(2) photosensitizer increased 19-fold.

  DOI：

  10.1021/ol3008843