1-(4-pyridylaminocarbonyl)cobalticinium tetraphenylborate | 164264-63-5

• 英文名称: 1-(4-pyridylaminocarbonyl)cobalticinium tetraphenylborate
• CAS: 164264-63-5
• 化学式: C₁₆H₁₄CoN₂O*C₂₄H₂₀B
• 分子量: 628.527
• InChiKey: JDOUOFHMRGRZRM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  potassium tetrachloroplatinate(II) 、 1-(4-pyridylaminocarbonyl)cobalticinium tetraphenylborate 以 甲醇 、 水 为溶剂， 以57%的产率得到bis(1-4-pyridylaminocarbonyl)cobalticinium dichloroplatinate bishexafluorophosphate
  参考文献：
  名称：

  Anion recognition by amide-linked pyridyl and pyridinium substituted cobalticinium receptors

  摘要：

  New acyclic mono- and 1,1'-bis-amide-linked pyridyl and pyridinium substituted cobalticinium ligands have been prepared. H-1 NMR anion coordination studies reveal that these ligands form 1:1 stoichiometric solution anion complexes with halides, HSO4- and H2PO4-. Stability constant determinations suggest that the pyridinium cobalticinium derivatives form stronger chloride anion complexes than their pyridyl analogues. Cyclic voltammetric investigations show that all these new cobalticinium derivatives electrochemically recognize halide, HSO4- and H2PO4- guest anions.

  DOI：

  10.1016/0277-5387(94)00325-9
• 作为产物：
  描述：

  4-氨基吡啶 、 cobaltocenium monocarboxylic acid chloride hexafluorophosphate 、 四苯硼钠 在 三乙胺 作用下， 以 乙腈 为溶剂， 以66%的产率得到1-(4-pyridylaminocarbonyl)cobalticinium tetraphenylborate
  参考文献：
  名称：

  Anion recognition by amide-linked pyridyl and pyridinium substituted cobalticinium receptors

  摘要：

  New acyclic mono- and 1,1'-bis-amide-linked pyridyl and pyridinium substituted cobalticinium ligands have been prepared. H-1 NMR anion coordination studies reveal that these ligands form 1:1 stoichiometric solution anion complexes with halides, HSO4- and H2PO4-. Stability constant determinations suggest that the pyridinium cobalticinium derivatives form stronger chloride anion complexes than their pyridyl analogues. Cyclic voltammetric investigations show that all these new cobalticinium derivatives electrochemically recognize halide, HSO4- and H2PO4- guest anions.

  DOI：

  10.1016/0277-5387(94)00325-9