| 1261219-69-5

• CAS: 1261219-69-5
• 化学式: C₄₈H₆₄Al₂F₁₀N₆O₂
• 分子量: 1001.02
• InChiKey: MDZDXLCHAFQZBL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  乙二醇二甲醚 、 双(五氟苯基)汞 、 3,5-二叔丁基-1H-吡唑 、 氢化铝 在 Hg 作用下， 以 乙二醇二甲醚 为溶剂， 以23%的产率得到
  参考文献：
  名称：

  Successful extrapolation of an f-element synthetic method to the pseudo light lanthanoid, aluminium

  摘要：

  A redox transmetallation/ligand exchange reaction between Al metal, Hg(C6F5)(2) and 3,5-di-tert-butyl-pyrazole (tBu(2)pzH) in tetrahydrofuran (thf) yields [Al(tBu(2)pz)(3)(thf)] in which the six coordinate aluminium atom has two eta(2)- and one eta(1)-tBu(2)pz ligands. By contrast an analogous reaction in 1,2-dimethoxyethane (dme) gives the organoaluminium complex [Al-2(tBu(2)pz)(3)(C6F5)(2)(OCH2CH2OCH3)] in which each aluminium atom has an eta(2)-pyrazolate and a C6F5 ligand and the Al atoms are bridged by an eta(1):eta(1)-tBu(2)pz ligand and a 2-methoxyethoxide ligand. In addition, [Al(tBu(2)pz)(3)] was isolated from the reaction mixture in a different form from that previously reprinted. (c) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.08.007