| 202461-41-4

• CAS: 202461-41-4
• 化学式: C₁₇H₃₀ClOPRu
• 分子量: 417.921
• InChiKey: FTCIESOPOLULIJ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 四(3,5-二(三氟甲基)苯基)硼酸钠 以 氟苯 为溶剂， 以70%的产率得到[((C5(CH3)5)Ru(CO)(P(CH3)(CH(CH3)2)2))2(μ-Cl)](tetrakis(3,5-bis(trifluoromethyl)phenyl)borate)
  参考文献：
  名称：

  Preparation and Reactivity of Organometallic Complexes Bearing the Fragment “Cp*Ru(CO)(PR₃)” (PR₃ = PMeⁱPr₂, PEt₃):  Dinuclear Complexes [{Cp*Ru(CO)(PR₃)}₂(μ-Cl)]⁺ Containing Two Chiral Centers, η²-Alkene, and Other Mononuclear Complexes

  摘要：

  The reactions of [Cp*RuCl(CO)((PMePr2)-Pr-i)] (1) and [Cp*RuCl(CO)(PEt3)] (2) with NaBAr'(4) in fluorobenzene both under argon and under dinitrogen generate the binuclear compounds [{Cp*Ru(CO)((PMePr2)-Pr-i)}(2)(mu-Cl)] [BAr'(4)] (3) and [{Cp*Ru(CO)(PEt3)}(2)(mu-Cl)][BAr'(4)] (4), respectively, which were fully characterized. The crystal structure of compound 4 is reported, showing for the first time two chiral "Cp*Ru" fragments bonded through only one bridging chloride ligand. No dinitrogen complexes or 16-electron species could be isolated. Halide abstraction from 1 using dry acetone as solvent yields the compound [Cp*Ru(CO){eta(1)-OC-(CH3)(2)}((PMePr2)-Pr-i)][BAr'(4)] (5). A range of olefins react with [Cp*RuCl(CO)((PMePr2)-Pr-i)] and NaBAr'(4) furnishing the corresponding cationic eta(2)-alkene complexes [Cp*Ru(CO)(L)((PMePr2)-Pr-i)] [BAr'(4)] (L = C2H4, 6; H2C = CHPh, 7; and H2C = CHCOOCH3, 8), which are stable under argon atmosphere in solution. The crystal structure of compound 6 is also reported. Both 1 and 2 react with SnCl2 in CH2Cl2 to yield the insertion derivatives [Cp*Ru(CO)(SnCl3)(PR3)] (PR3 = (PMePr2)-Pr-i, 9; PEt3, 10), which have also been characterized.

  DOI：

  10.1021/om034186x
• 作为产物：
  描述：

  bis[dichloro(pentamethylcyclopentadienyl)ruthenium(III)] 、 一氧化碳 、 三乙基膦 在 Zn 作用下， 以 四氢呋喃 为溶剂， 以60%的产率得到
  参考文献：
  名称：

  Preparation and Reactivity of Organometallic Complexes Bearing the Fragment “Cp*Ru(CO)(PR₃)” (PR₃ = PMeⁱPr₂, PEt₃):  Dinuclear Complexes [{Cp*Ru(CO)(PR₃)}₂(μ-Cl)]⁺ Containing Two Chiral Centers, η²-Alkene, and Other Mononuclear Complexes

  摘要：

  The reactions of [Cp*RuCl(CO)((PMePr2)-Pr-i)] (1) and [Cp*RuCl(CO)(PEt3)] (2) with NaBAr'(4) in fluorobenzene both under argon and under dinitrogen generate the binuclear compounds [{Cp*Ru(CO)((PMePr2)-Pr-i)}(2)(mu-Cl)] [BAr'(4)] (3) and [{Cp*Ru(CO)(PEt3)}(2)(mu-Cl)][BAr'(4)] (4), respectively, which were fully characterized. The crystal structure of compound 4 is reported, showing for the first time two chiral "Cp*Ru" fragments bonded through only one bridging chloride ligand. No dinitrogen complexes or 16-electron species could be isolated. Halide abstraction from 1 using dry acetone as solvent yields the compound [Cp*Ru(CO){eta(1)-OC-(CH3)(2)}((PMePr2)-Pr-i)][BAr'(4)] (5). A range of olefins react with [Cp*RuCl(CO)((PMePr2)-Pr-i)] and NaBAr'(4) furnishing the corresponding cationic eta(2)-alkene complexes [Cp*Ru(CO)(L)((PMePr2)-Pr-i)] [BAr'(4)] (L = C2H4, 6; H2C = CHPh, 7; and H2C = CHCOOCH3, 8), which are stable under argon atmosphere in solution. The crystal structure of compound 6 is also reported. Both 1 and 2 react with SnCl2 in CH2Cl2 to yield the insertion derivatives [Cp*Ru(CO)(SnCl3)(PR3)] (PR3 = (PMePr2)-Pr-i, 9; PEt3, 10), which have also been characterized.

  DOI：

  10.1021/om034186x