pentacabonyl[(phenyl)(pyrrol-1-yl)carbene]tungsten(0) | 165059-70-1

• 英文名称: pentacabonyl[(phenyl)(pyrrol-1-yl)carbene]tungsten(0)
• CAS: 165059-70-1
• 化学式: C₁₆H₉NO₅W
• 分子量: 479.101
• InChiKey: KYYIZTFSXKTTAE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  吡咯 、 pentacarbonyl(methoxyphenylmethylene)tungsten(0) 在 正丁基锂 、 水 作用下， 以 四氢呋喃 为溶剂， 以89%的产率得到pentacabonyl[(phenyl)(pyrrol-1-yl)carbene]tungsten(0)
  参考文献：
  名称：

  Group 6 Pyrrolocarbene Complexes as Alkoxycarbene Complex Analogs

  摘要：

  Chromium, molybdenum, and tungsten carbene complexes;having the pyrrole group as the heteroatom-containing substituent were synthesized and characterized. Their thermal and photochemical reactivity more nearly resembled that of alkoxycarbene complexes than that of aminocarbene complexes. Thus, they cyclopropanated electron deficient olefins, produced hydroquinones rather than indenes in the Dotz annulation process, and underwent photochemical 2 + 2 cycloaddition with alkenes to produce cyclobutanones and with imines to produce beta-lactams. With cyclohexadiene and cycloheptadiene, an unusual 4 + 2 cycloaddition of the diene across the ketene carbonyl group was observed. The pyrrole group was oxidatively cleaved to the corresponding formamide, the hydrolysis of which gave the free NH2 group, making the pyrrole group functionally equivalent to the amino group.

  DOI：

  10.1021/om00005a058