(tert-butylphosphirane)pentacarbonyltungsten | 188658-06-2

• 英文名称: (tert-butylphosphirane)pentacarbonyltungsten
• CAS: 188658-06-2
• 化学式: C₁₁H₁₃O₅PW
• 分子量: 440.045
• InChiKey: GXQJWAXBIHNQRO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  六羰基钨 、 tert-butylphosphirane 在 THF 作用下， 以 四氢呋喃 、 乙醚 为溶剂， 以90%的产率得到(tert-butylphosphirane)pentacarbonyltungsten
  参考文献：
  名称：

  Synthesis and Reactivity of Phosphirane Ligands and the Structural Characterization of Cp*IrCl₂(tert-butylphosphirane)

  摘要：

  New and stable phosphiranes, tert-butylphosphirane and xylylphosphirane, were prepared. tert-Butylphosphirane is stable to polymerization in the presence of electrophiles. It was reacted with bis((mu-chloro)chloro(pentamethylcyclopentadienyl)iridium) to prepare (tert-butylphosphirane)dichloro(pentamethylcyclopentadienyl)iridium, which was characterized by X-ray diffraction, tert-Butylphosphirane was also reacted with pentacarbonyl(tetrahydrofuran)tungsten and borane to form (tert-butylphosphirane)pentacarbonyltungsten and the first phosphirane-borane adduct, respectively.

  DOI：

  10.1021/om960400o