[(2-[(2-pyridylmethoxy)methyl]pyridine)RuCl(triphenylphosphine)2](BF4) | 1196073-58-1

• 英文名称: [(2-[(2-pyridylmethoxy)methyl]pyridine)RuCl(triphenylphosphine)2](BF4)
• CAS: 1196073-58-1
• 化学式: BF₄*C₄₈H₄₂ClN₂OP₂Ru
• 分子量: 948.149
• InChiKey: GICRIRURBPEEAW-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  tris(triphenylphosphine)ruthenium(II) chloride 、 氟硼酸铵 、 bis(2-pyridylmethyl)ether 以 甲醇 为溶剂， 以80%的产率得到[(2-[(2-pyridylmethoxy)methyl]pyridine)RuCl(triphenylphosphine)2](BF4)
  参考文献：
  名称：

  Preparation, characterization, and catalytic properties of (triphenylphosphine)ruthenium complexes bearing N,O,N′-tridentate ligands

  摘要：

  Preparation and characterization of (triphenylphosphine)ruthenium complexes bearing N,O,N'-tridentate ligands, [(L-1)RuCl(PPh3)(2)](BF4) (L-1 = 2-[(2-pyridylmethoxy)methyl] pyridine), 1), [(L-2)RuCl(PPh3)(2)](BF4) (L-2 = 8-(2-pyridylmethoxy)quinoline, 2) and [(L-3)RuCl2(PPh3)] (L-3 = 2-[(2-pyridylmethoxy)methyl] quinoline, 3) are described. Complexes 1-3 have been characterized by NMR and elemental analyses. Molecular structures of 2 and 3 have been determined by X-ray crystallography. Both compounds exhibit the octahedral geometry. L-2 adopts the facial configuration in 2 while L-3 is in a mer-arrangement in 3. Complexes 1-3 have proven to be able to catalyze the transfer hydrogenation of several ketones to alcohols in the presence of KOH and 2-propanol at refluxing, among which complex 3 was found to be the most active. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.06.055