| 795277-37-1

• CAS: 795277-37-1
• 化学式: C₁₇H₂₁ClFeO₂
• 分子量: 348.653
• InChiKey: MGHOQWRNFPFPER-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  3,6-di(thiophen-2-yl)-9H-carbazole 、 在 potassium hydroxide 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 25.0h， 以69%的产率得到6-(3,6-di(thiophen-2-yl)-9H-carbazol-9-yl)hexyl ferrocenecarboxylate
  参考文献：
  名称：

  二茂铁官能化聚(6-(3,6-di(thiophen-2-yl)-9H-carbazol-9-yl)-hexyl Ferrocenecarboxylate)：二茂铁对电致变色性能的影响

  摘要：

  A novel ferrocene-containing compound 6-(3,6-di(thiophen-2-yl)-9H-carbazol-9-yl)hexyl ferrocenecarboxylate (BTC-H-Fc) was synthesized by simple chemical route, and 3,6-di(thiophen-2-yl)-9H-carbazole (BTC) was prepared for comparison. Both of the homopolymers of BTC-H-Fc and BTC were successfully synthesized by electropolymerization and kept the redox activity upon repeated cycling between 0.0 V and 1.4 V. Compared to PBTC which could only showed two colors (yellow and purple), P(BTC-H-Fc) film could exhibit four colors (yellow, awny, purple and indigo-blue) as a consequence of mixing colors of main chain and Fc group. Meanwhile, P(BTC-H-Fc) film presented higher optical contrast of 52% and more excellent coloration efficiency (573.72 cm(2) C-1). All the results demonstrate that Fc could be a good choice as a functional group to improve the electrochromic properties of the electrochromic polymers. (C) 2014 The Electrochemical Society. All rights reserved.

  DOI：

  10.1149/2.076405jes
• 作为产物：
  描述：

  二茂铁甲酸 、 6-氯-1-己醇 在 4-二甲氨基吡啶 、 盐酸-N-乙基-Nˊ-(3-二甲氨基丙基)碳二亚胺 作用下， 以 二氯甲烷 为溶剂， 反应 24.0h， 以77%的产率得到
  参考文献：
  名称：

  二茂铁官能化聚(6-(3,6-di(thiophen-2-yl)-9H-carbazol-9-yl)-hexyl Ferrocenecarboxylate)：二茂铁对电致变色性能的影响

  摘要：

  A novel ferrocene-containing compound 6-(3,6-di(thiophen-2-yl)-9H-carbazol-9-yl)hexyl ferrocenecarboxylate (BTC-H-Fc) was synthesized by simple chemical route, and 3,6-di(thiophen-2-yl)-9H-carbazole (BTC) was prepared for comparison. Both of the homopolymers of BTC-H-Fc and BTC were successfully synthesized by electropolymerization and kept the redox activity upon repeated cycling between 0.0 V and 1.4 V. Compared to PBTC which could only showed two colors (yellow and purple), P(BTC-H-Fc) film could exhibit four colors (yellow, awny, purple and indigo-blue) as a consequence of mixing colors of main chain and Fc group. Meanwhile, P(BTC-H-Fc) film presented higher optical contrast of 52% and more excellent coloration efficiency (573.72 cm(2) C-1). All the results demonstrate that Fc could be a good choice as a functional group to improve the electrochromic properties of the electrochromic polymers. (C) 2014 The Electrochemical Society. All rights reserved.

  DOI：

  10.1149/2.076405jes