(Me2Ge)[(η(5)-C5H4)Ru(CO)]2(μ-CO)2 | 198199-35-8

• 英文名称: (Me2Ge)[(η(5)-C5H4)Ru(CO)]2(μ-CO)2
• CAS: 198199-35-8
• 化学式: C₁₆H₁₄GeO₄Ru₂
• 分子量: 545.015
• InChiKey: PQRCXZICFNTEAJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  tin(II) chloride dihdyrate 、 (Me2Ge)[(η(5)-C5H4)Ru(CO)]2(μ-CO)2 以 四氢呋喃 为溶剂， 以91%的产率得到(Me2Ge)[(η(5)-C5H4)Ru(CO)2]2SnCl2
  参考文献：
  名称：

  Insertion of SnCl2 into the metal-metal bonds in bridged binuclear complexes (Me2E)[(η5-C5H4)M(CO)]2(μ-CO)2 (ESi, Ge; MFe, Ru. (The molecular structure of (Me2Ge)[(η5-C5H4)Fe(CO)2]2SnCl2

  摘要：

  The synthesis of bridged binuclear complexes (Me2E)[(eta(5)-C5H4)M(CO)](2)(mu-CO)(2) [E = Si, M = Ru (3); E = Ge, M = Fe (2), M = Ru (4)] is described. Insertion of SnCl2 into the metal-metal bonds in these complexes affords a type of hetero-nuclear cyclic metallic complexes (Me2E)[(eta(5)-C5H4)M(CO)(2)](2)SnCl2 [E = Si, M = Ru (7); E = Ge, M = Fe (6), M = Ru (8)]. Complex 6 reacts with Grignard reagents RMgX to yield alkyl (or aryl)-substituted analogues (Me2Ge)[(eta(5)-C5H4)Fe(CO)(2)](2)SnR2 [R = Me (9); R = Ph (10)]. AU of the complexes were characterized by IR, H-1 NMR and elementary analysis. Both 6 and 8 are still characterized by Sn-119 NMR. The molecular structure of 6 has been determined by X-ray diffraction. Crystals of 6 are orthorhombic, space group Pcab with a = 13.499(2) Angstrom, b = 16.883(6) Angstrom, c = 18.368(4) Angstrom, V = 4168(3) Angstrom(3), Z = 8, Dx = 2.044 g cm(-3), R (R-w)= 0.044 (0.059). (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00312-4