4,4-difluoro-8-[3',5'-bis(decyloxy)phenyl]-2,6-diiodo-1,3,5,7-tetramethyl-4-bora-3a,4a-diaza-s-indacene | 1094812-00-6

• 英文名称: 4,4-difluoro-8-[3',5'-bis(decyloxy)phenyl]-2,6-diiodo-1,3,5,7-tetramethyl-4-bora-3a,4a-diaza-s-indacene
• 英文别名: 4,4-difluoro-8-(3,5-bis(decyloxy)phenyl)-2,6-diiodo-1,3,5,7-tetramethyl-4-bora-3a,4a-diaza-s-indacene
• CAS: 1094812-00-6
• 化学式: C₃₉H₅₇BF₂I₂N₂O₂
• 分子量: 888.511
• InChiKey: LEQQANIWBOSMHL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  4,4-difluoro-8-[3',5'-bis(decyloxy)phenyl]-2,6-diiodo-1,3,5,7-tetramethyl-4-bora-3a,4a-diaza-s-indacene 、 5-乙炔基-2-吡啶-2-基吡啶 在 bis-triphenylphosphine-palladium(II) chloride 、 copper(l) iodide 、 二异丙胺 作用下， 以 四氢呋喃 为溶剂， 反应 24.0h， 以80%的产率得到4,4-difluoro-8-[3',5'-bis(decyloxy)phenyl]-2,6-bis(2'',2'''-bipyridine-5''-ethynyl)-1,3,5,7-tetramethyl-4-bora-3a,4a-diaza-s-indacene
  参考文献：
  名称：

  基于硼氮杂吲哚发色团的新型分子构件：在荧光金属超分子配位聚合物中的应用

  摘要：

  明亮的聚合物：描述了由通用的官能化双联吡啶（硼双联吡啶）生色团组成的荧光配位聚合物，如图所示。聚合是通过荧光发射强度的变化和峰值发射波长的变化来表示的。

  DOI：

  10.1002/chem.200802538
• 作为产物：
  描述：

  4,4-difluoro-8-[3',5'-bis(decyloxy)phenyl]-2-iodo-1,3,5,7-tetramethyl-4-bora-3a,4a-diaza-s-indacene 在 碘 、 碘酸 作用下， 以 水 为溶剂， 以95%的产率得到4,4-difluoro-8-[3',5'-bis(decyloxy)phenyl]-2,6-diiodo-1,3,5,7-tetramethyl-4-bora-3a,4a-diaza-s-indacene
  参考文献：
  名称：

  Phenylethynyl-BODIPY Oligomers: Bright Dyes and Fluorescent Building Blocks

  摘要：

  Boradiazaindacene dyes were converted Into phenylethynyl-BODIPY oligomers via a cycle of reactions, notably including Sonogashira couplings. As expected, as the number, n, of repeating units Increases, peak absorption and emission wavelengths are shifted to the red end of the visible spectrum, albeit with smaller increments as n Increases, Decyl groups help to keep the solubility remarkably high, and in addition to being very bright red-emitting fluorophores, their rigid rod-like structures could allow their use as functional building blocks.

  DOI：

  10.1021/ol802446e

文献信息

• Tetrastyryl-Bodipy Dyes: Convenient Synthesis and Characterization of Elusive Near IR Fluorophores
  作者：Onur Buyukcakir、O. Altan Bozdemir、Safacan Kolemen、Sundus Erbas、Engin U. Akkaya

  DOI：10.1021/ol9019056

  日期：2009.10.15

  1,3,5,7-Tetramethyl-Bodipy derivatives undergo Knoevenagel-type condensations with aromatic aldehydes to ultimately yield tetrastyryl-Bodipy derivatives. The resulting dyes absorb and emit strongly in the near IR. As the versatility of the Bodipy dyes are fully appreciated, these new tetrastyryl dyes are likely to be featured in a variety of functional supramolecular systems.