Einecs 235-359-4 | 12187-46-1

• 分子结构分类: 无机化合物 - 均相金属化合物 - 金属间过渡金属化合物
• 英文名称: Einecs 235-359-4
• 英文别名: cobalt;samarium
• CAS: 12187-46-1
• 化学式: Co₃Sm
• 分子量: 327.34
• InChiKey: SBLDVTJDWWKDPL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Einecs 235-359-4 、 氢气 生成
  参考文献：
  名称：

  Shilov, A. L.; Yaropolova, E. I.; Kost, M. E., Doklady Chemistry, 1980, vol. 252, p. 313 - 316

  摘要：

  DOI：
• 作为产物：
  描述：

  氯化钐 、 cobalt(II) chloride 以 melt 为溶剂， 生成 Einecs 235-359-4
  参考文献：
  名称：

  Electrochemical formation of Sm–Co alloys by codeposition of Sm and Co in a molten LiCl–KCl–SmCl3–CoCl2 system

  摘要：

  Electrocodeposition of Sm and Co on a Cu substrate was investigated in a molten LiCl-KCl-SmCl3 (0.5 mol.%)-CoCl2 (0.1 mol.%) system at 723 K. Phase of the deposited Sm-Co alloys could be controlled by electrolysis potential. SmCo3 was formed on a Cu substrate by potentiostatic electrolysis in the potential range of 0.20-0.90 V (vs. Li+/Li). Sm2Co17 was obtained in the potential range of 0.90-1.50 V. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0013-4686(03)00293-7

文献信息

• Formation of Sm-Co Intermetallic Compound Nanoparticles Based on Plasma-Induced Cathodic Discharge Electrolysis in Chloride Melt
  作者：M. Tokushige、H. Hongo、T. Nishikiori、Y. Ito

  DOI：10.1149/2.012201jes

  日期：——

  Sm-Co intermetallic compound nanoparticles were obtained by utilizing plasma-induced cathodic discharge electrolysis in molten chloride electrolyte under a 1 atm Ar atmosphere. To form intermetallic nanoparticle, an electrochemical implantation method was adopted. Before conducting electrochemical implantation, we investigated the electrolytic condition to form Co nanoparticle to be used as a precursor. The size and crystal structure of the obtained Co nanoparticle strongly depended on the melt temperature. Hexagonal petaline epsilon-Co nanoparticles were obtained below 400 degrees C, and spherical alpha-Co nanoparticles were obtained above 400 degrees C. The size of the obtained spherical alpha-Co particle increased from 112 to 230 nm with increasing melt temperature. Using spherical alpha-Co nanoparticles, which were formed at 450 degrees C in the melt by plasma-induced cathodic discharge electrolysis and piled-up on the Mo plate as a working electrode, SmCo2 and SmCo3 intermetallic nanoparticles were obtained by electrochemical implantation of Sm into alpha-Co nanoparticles. (C) 2011 The Electrochemical Society. [DOI: 10.1149/2.012201jes]
• Microstructures and coercivities of SmCo and Sm(Co,Cu)5 films prepared by magnetron sputtering
  作者：J. Zhang、Y.K. Takahashi、R. Gopalan、K. Hono

  DOI：10.1016/j.jmmm.2006.07.017

  日期：2007.3
• Hydrogenation of alloys of rare-earth metals
  作者：M. E. Kost、A. L. Shilov

  DOI：10.1007/bf01167748

  日期：1983.1