摘要:
The complexes [(eta(5)-C5H5)Fe(CO)(2)(SCdropCR)] (R = 'Bu, SiMe3) have been obtained by reaction of [(eta(5)-C5H5)Fe(CO)(2)I] and the corresponding LiSCdropCR. These are the first examples of mononuclear iron compounds containing alkynethiolate ligands. The crystal structure of [(eta(5)-C5H5)Fe(CO)(2)(SCdropCSiMe(3))] has been determined by X-ray diffraction. The role of [(eta(5)-C5H5)Fe(CO)(2)(SCdropCSiMe(3))] as a metalloligand in its reactions with metal carbonyls has been explored. (C) 2002 Elsevier Science B.V. All rights reserved.