| 445042-75-1

• CAS: 445042-75-1
• 化学式: C₁₈H₁₄Co₂FeO₈SSi
• 分子量: 592.289
• InChiKey: LRSBEDSXWJAJCS-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dicobalt octacarbonyl 、 以 四氢呋喃 为溶剂， 以72%的产率得到
  参考文献：
  名称：

  Alkynethiolate ligands in the syntheses of iron carbonyl derivatives. Crystal structure of [(η5-C5H5)Fe(CO)2(SCCSiMe3)]

  摘要：

  The complexes [(eta(5)-C5H5)Fe(CO)(2)(SCdropCR)] (R = 'Bu, SiMe3) have been obtained by reaction of [(eta(5)-C5H5)Fe(CO)(2)I] and the corresponding LiSCdropCR. These are the first examples of mononuclear iron compounds containing alkynethiolate ligands. The crystal structure of [(eta(5)-C5H5)Fe(CO)(2)(SCdropCSiMe(3))] has been determined by X-ray diffraction. The role of [(eta(5)-C5H5)Fe(CO)(2)(SCdropCSiMe(3))] as a metalloligand in its reactions with metal carbonyls has been explored. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01444-9