dicarbonyl[η5-2,3,4,5-tetramethyl-1-(8-quinolyl)cyclopentadienyl]rhodium(I) | 779341-07-0

• 英文名称: dicarbonyl[η5-2,3,4,5-tetramethyl-1-(8-quinolyl)cyclopentadienyl]rhodium(I)
• CAS: 779341-07-0
• 化学式: C₂₀H₁₈NO₂Rh
• 分子量: 407.274
• InChiKey: FILOOJHNXXXAKW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  氘代氯仿 、 dicarbonyl[η5-2,3,4,5-tetramethyl-1-(8-quinolyl)cyclopentadienyl]rhodium(I) 以 氘代氯仿 为溶剂， 生成 [η5-2,3,4,5-tetramethyl-1-(8-quinolyl)cyclopentadienyl]dichloridorhodium(III)
  参考文献：
  名称：

  Rhodium-carbonyl complexes with a quinolyl functionalized Cp-ligand: synthesis and photochemical activation

  摘要：

  Dicarbonyl[eta(5)-2,3,4,5-tetramethyl-1-(8-quinolyl)cyclopentadienyl]rhodium(I) (1) was prepared by the reaction of [Rh(CO2)Cl](2) with 2,3,4,5-tetramethyl-1-(8-quinolyl)cyclopentadienyl-potassium. Irradiation of 1 in chloroform or dichloromethane as solvent leads to the formation of dichloro[eta(5)-2,3,4,5-tetramethyl-1-(8-quinolyl)cyclopentadienyl]rhodium(III) (2). When Rh-6(CO)(16) is present, the cluster adds to the 8-quinolyl-cp-rhodium fragment and the compound [eta(5)-2,3,4,5-tetramethyl-l-(8-quinolyl)cyclopentadie-nyl]rhodium-di-mu-carbonyl-hexarhodiumtetradecacarbonyl (3) is formed in 65% yield. The coordination sphere of the rhodium(III) atom in compound 2 and of the rhodium(I) atom in 3 is completed by a coordination of the quinolyl moiety. This was revealed by NMR spectroscopy as well as by X-ray analyses. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.06.046
• 作为产物：
  描述：

  2,3,4,5-tetramethyl-1-(8-quinolyl)cyclopentadiene 、 di(rhodium)tetracarbonyl dichloride 在 KH 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 以56%的产率得到dicarbonyl[η5-2,3,4,5-tetramethyl-1-(8-quinolyl)cyclopentadienyl]rhodium(I)
  参考文献：
  名称：

  Rhodium-carbonyl complexes with a quinolyl functionalized Cp-ligand: synthesis and photochemical activation

  摘要：

  Dicarbonyl[eta(5)-2,3,4,5-tetramethyl-1-(8-quinolyl)cyclopentadienyl]rhodium(I) (1) was prepared by the reaction of [Rh(CO2)Cl](2) with 2,3,4,5-tetramethyl-1-(8-quinolyl)cyclopentadienyl-potassium. Irradiation of 1 in chloroform or dichloromethane as solvent leads to the formation of dichloro[eta(5)-2,3,4,5-tetramethyl-1-(8-quinolyl)cyclopentadienyl]rhodium(III) (2). When Rh-6(CO)(16) is present, the cluster adds to the 8-quinolyl-cp-rhodium fragment and the compound [eta(5)-2,3,4,5-tetramethyl-l-(8-quinolyl)cyclopentadie-nyl]rhodium-di-mu-carbonyl-hexarhodiumtetradecacarbonyl (3) is formed in 65% yield. The coordination sphere of the rhodium(III) atom in compound 2 and of the rhodium(I) atom in 3 is completed by a coordination of the quinolyl moiety. This was revealed by NMR spectroscopy as well as by X-ray analyses. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.06.046