2-ferrocenyl-4,5-diamino-1H-benzo[d]imidazole | 1266103-82-5

• 英文名称: 2-ferrocenyl-4,5-diamino-1H-benzo[d]imidazole
• CAS: 1266103-82-5
• 化学式: C₁₇H₁₆FeN₄
• 分子量: 332.188
• InChiKey: CXZHCLDBGJTQJY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  二茂铁甲醛 、 2-ferrocenyl-4,5-diamino-1H-benzo[d]imidazole 在 溶剂黄146 作用下， 以 硝基苯 为溶剂， 反应 12.0h， 以43%的产率得到2,7-diferrocenyl-1,6-dihydrobenzo[1,2-d:3,4-d']bisimidazole
  参考文献：
  名称：

  Ferrocenylbenzobisimidazoles for Recognition of Anions and Cations

  摘要：

  The preparation of 2,7-disubstituted benzobisimidazoles decorated with substituents displaying different electrooptical properties is described. The presence of reclox, chromogenic, and fluorescent groups at the heteroaromatic core, which acts as ditopic binding site, made these receptors potential candidates as multichannel probes for ions. The triad 4 behaves as a selective redox and fluorescent chemosensor for HSO4- and Hg2+ ions, whereas receptor 5 acts as a redox and chromogenic chemosensor molecule for AcO- and SO42- anions. The change in the absorption spectra is accompanied by a color change from yellow to orange, while sensing of Zn2+, Hg2+ and Pb2+ cations is carried out only by electrochemical techniques. Receptor 6 exhibits a remarkable cathodic shift of the oxidation wave only in the presence of AcO-, H2PO4-, and HP2O73- anions, whereas addition of Pb2+ induces an anodic shift. A new low energy band in the absorption spectra, which is responsible for the color change from colorless to pale yellow, and an important increase of the monomer emission band is observed only in the presence of H2PO4-, and HP2O73- anions. The most salient feature of the receptor 6 is its ability to act as a multichannel (redox, chromogenic, and fluorescent) Chemodosimeter for Cu2+, and Hg2+ metal cations.

  DOI：

  10.1021/ic400365c
• 作为产物：
  描述：

  7-ferrocenyl-8H-imidazo[4,5-e]-2,1,3-benzothiadiazole 在 sodium tetrahydroborate 、 cobalt(II) chloride hexahydrate 作用下， 以 乙醇 为溶剂， 反应 3.0h， 生成 2-ferrocenyl-4,5-diamino-1H-benzo[d]imidazole
  参考文献：
  名称：

  制备和富氮二茂铁-咪唑-喹喔啉的传感特性与吡咯环黑社会装饰†

  摘要：

  富氮二茂铁-咪唑-喹喔啉的合成和传感特性三元组1的装饰具有两个吡咯环已被描述。由于其双中心性质，该分子表现为对镍离子对受体2+阳离子和ACO -阴离子，虽然无论是离散的离子的非亲合性是观察。它还显示了与离子对的协同AND识别相一致的稀有特性。因此，该受体示出了用于结合ACO重要的增强-阴离子，当它是共同绑定到汞2+阳离子，而观察到由阴离子的游离受体没有亲和性。

  DOI：

  10.1039/c6dt03667h

文献信息

• Highly selective mercury(ii) cations detection in mixed–aqueous media by a ferrocene-based fluorescent receptor
  作者：María Alfonso、Julia Contreras-García、Arturo Espinosa、Alberto Tárraga、Pedro Molina

  DOI：10.1039/c2dt12156e

  日期：——

  A new chemosensor molecule 3 based on a ferrocene–imidazophenanthrophenazine dyad effectively recognizes Hg2+ in an aqueous environment through three different channels. Upon recognition, an anodic shift of the ferrocene–ferrocenium oxidation potential (ΔE1/2 = 240 mV) and a progressive red shift (Δλ = 17 nm) of the low energy band in its absorption spectrum is produced. The emission spectrum of 3 in an aqueous environment, CH3CN–EtOH–H2O (65 : 25 : 10), and conducted at pH = 7.4 (20 × 10−3 M HEPES) (Φ = 0.003), is perturbed after addition of Hg2+ cations and an intense and structureless red shift emission band at 494 nm (Δλ = 92 nm) appeared along with an increase of the intensity of the emission band (CHEF = 77), the quantum yield (Φ = 0.054) resulted in a 18-fold increase. The combined 1H NMR data of the complex and the theoretical calculations suggest the proposed bridging coordination mode.

  一种新的化学传感器分子 3 基于二茂铁咪唑吩吩蒽嗪二元化合物，通过三种不同的途径有效识别水环境中的 Hg2+。识别后，二茂铁的氧化电位会发生阳移（δE1/2 = 240 mV），其吸收光谱中的低能段会发生渐进的红移（δ" = 17 nm）。3 在水环境 CH3CNâEtOHâH2O (65â:â25â:â10) 中的发射光谱在 pH = 7.4 (20 Ã 10â3 M HEPES) 条件下进行（δ = 0.在加入 Hg2+ 阳离子后，494 nm（δ" = 92 nm）处的无结构红移发射带受到扰动，同时发射带强度（CHEF = 77）增加，量子产率（δ = 0.054）增加了 18 倍。该复合物的 1H NMR 数据和理论计算相结合，表明了所提出的桥接配位模式。