2-(2-Phenylphenyl)adamantan-2-ol | 727730-30-5

• 英文名称: 2-(2-Phenylphenyl)adamantan-2-ol
• CAS: 727730-30-5
• 化学式: C₂₂H₂₄O
• 分子量: 304.432
• InChiKey: RSSRWPLCQAQJJW-UHFFFAOYSA-N

物化性质

• 沸点：
  481.4±24.0 °C(Predicted)
• 密度：
  1.151±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  23
• 可旋转键数：
  2
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-(2-Phenylphenyl)adamantan-2-ol 在 盐酸 、 溴 、 溶剂黄146 作用下， 以 二氯甲烷 、 水 为溶剂， 生成 2',7'-二溴螺[金刚烷-2,9'-芴
  参考文献：
  名称：

  Sterically Encumbered Fluorene-Based Poly(arylene ether)s Containing Spiro-Annulated Substituents on the Main Chain

  摘要：

  Two novel fluorene based bisphenol monomers containing spiro annulated substituents on the middle biphenylene moiety have been synthesized in this study Through reacting with four 2-trifluoromethyl-activated bisfluoro monomers, two monomers were converted into a series of fluorene based poly(arylene ether)s by nucleophilic displacement of the fluorine atoms on the terminal benzene ring of bisfluoro monomers The obtained polymers exhibit weight average molecular weight up to 2 41 x 10(5) g/mol in GPC Thermal analysis studies indicated that these polymers did not show melting endotherms but did show ultrahigh T-g values up to 356 degrees C in DSC and outstanding thermal stability up to 643 degrees C for 5% weight loss in TGA under nitrogen atmosphere The polymers are soluble in a wide range of organic solvents, THF CHCl3, NMP DMAc DMF toluene, etc, and are insoluble in DMSO and acetone at room temperature Transparent and flexible films were easily prepared by solution casting from chloroform solution of each of the polymers

  DOI：

  10.1021/ma102093t
• 作为产物：
  描述：

  2-氨基联苯 在 盐酸 、 碘 、 magnesium 、 sodium nitrite 作用下， 以 乙醚 、 水 为溶剂， 反应 0.25h， 生成 2-(2-Phenylphenyl)adamantan-2-ol
  参考文献：
  名称：

  Sterically Encumbered Fluorene-Based Poly(arylene ether)s Containing Spiro-Annulated Substituents on the Main Chain

  摘要：

  Two novel fluorene based bisphenol monomers containing spiro annulated substituents on the middle biphenylene moiety have been synthesized in this study Through reacting with four 2-trifluoromethyl-activated bisfluoro monomers, two monomers were converted into a series of fluorene based poly(arylene ether)s by nucleophilic displacement of the fluorine atoms on the terminal benzene ring of bisfluoro monomers The obtained polymers exhibit weight average molecular weight up to 2 41 x 10(5) g/mol in GPC Thermal analysis studies indicated that these polymers did not show melting endotherms but did show ultrahigh T-g values up to 356 degrees C in DSC and outstanding thermal stability up to 643 degrees C for 5% weight loss in TGA under nitrogen atmosphere The polymers are soluble in a wide range of organic solvents, THF CHCl3, NMP DMAc DMF toluene, etc, and are insoluble in DMSO and acetone at room temperature Transparent and flexible films were easily prepared by solution casting from chloroform solution of each of the polymers

  DOI：

  10.1021/ma102093t

文献信息

• 有机化合物和电子装置
  申请人：陕西莱特光电材料股份有限公司

  公开号：CN111039881B

  公开（公告）日：2021-01-01

  本发明提供一种有机化合物及包含该有机化合物的电子装置，属于有机材料技术领域。该有机化合物的结构如下式(1)所示，其中Y的结构如下式(2)或(3)所示。该有机化合物用于例如有机电致发光器件的电子装置中，可以改善有机电致发光器件的寿命特性、效率特性、电化学稳定性和热稳定性并且降低驱动电压。
• 化合物、光电转化器件及电子装置
  申请人：陕西莱特光电材料股份有限公司

  公开号：CN110615759B

  公开（公告）日：2020-08-11

  本公开提供一种如式I所示的化合物、光电转化器件及电子装置，属于有机材料技术领域。该化合物能够降低光电转化器件的工作电压、提高光电转化器件的发光效率，并延长器件的寿命。
• Organic compound having adamantyl fluorene ligands on 1,3,5-triazine and electronic device
  申请人：Shaanxi Lighte Optoelectronics Material Co., Ltd.

  公开号：US11495748B2

  公开（公告）日：2022-11-08

  The present disclosure provides an organic compound and an electronic device containing the organic compound, which relates to the technical field of organic materials. The structure of the organic compound is as shown in the following Chemical formula (1), where Y has a structure as shown in the following formula (2) or (3). The organic compound is used in, for example, an electronic device of an organic electroluminescent device, and can improve the lifetime property and deficiency property, electrochemical stability and thermal stability, and reduce the driving voltage of the organic electroluminescent device.

  本公开提供了一种有机化合物和含有该有机化合物的电子设备，涉及有机材料技术领域。有机化合物的结构如下化学式（1）所示，其中 Y 的结构如下式（2）或（3）所示。该有机化合物用于例如有机电致发光器件的电子装置中，可改善有机电致发光器件的寿命特性和缺陷特性、电化学稳定性和热稳定性，并降低驱动电压。
• [EN] ORGANIC COMPOUND AND ELECTRONIC DEVICE<br/>[FR] COMPOSÉ ORGANIQUE ET DISPOSITIF ÉLECTRONIQUE<br/>[ZH] 有机化合物和电子装置
  申请人：SHAANXI LIGHTE OPTOELECTRONICS MAT CO LTD

  公开号：WO2021057550A1

  公开（公告）日：2021-04-01

  本发明提供了一种有机化合物及包含该有机化合物的电子装置，属于有机材料技术领域。该有机化合物的结构如下化学式1所示，其中Y的结构如下式(2)或(3)所示。该有机化合物用于例如有机电致发光器件的电子装置中，可以改善有机电致发光器件的寿命特性、效率特性、电化学稳定性和热稳定性并且降低驱动电压。
• ORGANIC COMPOUND AND ELECTRONIC DEVICE
  申请人：Shaanxi Lighte Optoelectronics Material Co., Ltd.

  公开号：US20220216420A1

  公开（公告）日：2022-07-07

  The present disclosure provides an organic compound and an electronic device containing the organic compound, which relates to the technical field of organic materials. The structure of the organic compound is as shown in the following Chemical formula (1), where Y has a structure as shown in the following formula (2) or (3). The organic compound is used in, for example, an electronic device of an organic electroluminescent device, and can improve the lifetime property and deficiency property, electrochemical stability and thermal stability, and reduce the driving voltage of the organic electroluminescent device.