| 509105-78-6

• CAS: 509105-78-6
• 化学式: C₄₆H₄₅ClRuSb₂
• 分子量: 977.886
• InChiKey: IUABBHHGZFFWHA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 氢气 、 四(3,5-二(三氟甲基)苯基)硼酸钠 以 氟苯 为溶剂， 以60%的产率得到[(C5Me5)Ru(H)2(Sb(C6H5)3)2][B(3,5-C6H3(CF3)2)4]
  参考文献：
  名称：

  Ruthenium hydrides bearing SbPh3 and AsPh3 ligands: characterization of the bis(dihydrogen) complexes [Cp*Ru(H2)2(EPh3)]+ (Cp*=C5Me5; E=Sb, As)

  摘要：

  Reaction of NaBH4 with [Cp*RUCl2(EPh3)] (E = Sb la, As 1b) in THF/EtOH affords the trihydride complexes [Cp*RuH3(EPh3)] (E = Sb 2a, As 2b) in good yield. These trihydrides are protonated by HBF4.OEt2 in CH2Cl2 at -80 degreesC furnishing the cationic bis(dihydrogen) complexes [Cp*Ru(H-2)(2)(EPh3)][BF4] (E = Sb 3a, As 3b), which were characterized in solution by T, and (1)J(HD) measurements. These species are unstable and decompose at T > 0 degreesC. The reaction of [Cp*RuCl(SbPh3)(2)] with H-2 and NaBAr4' in fluorobenzene yields the dihydride [Cp*RuH2(SbPh3)(2)][BAr4'] (5). Protonation of the monohydride [Cp*RuH(SbPh3)(2)] (6) by HBF4.OEt2 in CH2Cl2 at -80 degreesC generates the dihydrogen complex [Cp*Ru(H-2)(SbPh3)(2)](+) (7), which rearranges to its dihydride tautomer 5 when the temperature is raised. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01965-4
• 作为产物：
  描述：

  二氯(五甲基环戊二烯基)合钌(III)聚合物 、 三苯基锑 在 Zn 作用下， 以 四氢呋喃 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  Ruthenium hydrides bearing SbPh3 and AsPh3 ligands: characterization of the bis(dihydrogen) complexes [Cp*Ru(H2)2(EPh3)]+ (Cp*=C5Me5; E=Sb, As)

  摘要：

  Reaction of NaBH4 with [Cp*RUCl2(EPh3)] (E = Sb la, As 1b) in THF/EtOH affords the trihydride complexes [Cp*RuH3(EPh3)] (E = Sb 2a, As 2b) in good yield. These trihydrides are protonated by HBF4.OEt2 in CH2Cl2 at -80 degreesC furnishing the cationic bis(dihydrogen) complexes [Cp*Ru(H-2)(2)(EPh3)][BF4] (E = Sb 3a, As 3b), which were characterized in solution by T, and (1)J(HD) measurements. These species are unstable and decompose at T > 0 degreesC. The reaction of [Cp*RuCl(SbPh3)(2)] with H-2 and NaBAr4' in fluorobenzene yields the dihydride [Cp*RuH2(SbPh3)(2)][BAr4'] (5). Protonation of the monohydride [Cp*RuH(SbPh3)(2)] (6) by HBF4.OEt2 in CH2Cl2 at -80 degreesC generates the dihydrogen complex [Cp*Ru(H-2)(SbPh3)(2)](+) (7), which rearranges to its dihydride tautomer 5 when the temperature is raised. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01965-4