dicarbonylcyclopentadienyl(m-trifluoromethylphenyl)iron | 1083330-10-2

• 英文名称: dicarbonylcyclopentadienyl(m-trifluoromethylphenyl)iron
• 英文别名: [CpFe(CO)2C6H4-3-CF3]；CpFe(C6H4CF3-3)(CO)2
• CAS: 1083330-10-2
• 化学式: C₁₄H₉F₃FeO₂
• 分子量: 322.066
• InChiKey: TUSZBLDAAJGMLI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  苯乙烯 、 dicarbonylcyclopentadienyl(m-trifluoromethylphenyl)iron 以 5,5-dimethyl-1,3-cyclohexadiene 为溶剂， 反应 24.0h， 以58%的产率得到1-styryl-3-(trifluoromethyl)benzene
  参考文献：
  名称：

  Arylation of Styrenes with Aryliron Complexes [CpFe(CO)₂Ar]

  摘要：

  Treatment of aryliron complexes [CpFe(CO)(2)Ar] with styrenes in boiling xylene affords the corresponding stilbenes. The aryliron complexes, which become active upon heating, serve as arylating agents in the reaction.

  DOI：

  10.1021/om1001952
• 作为产物：
  描述：

  dicarbonylcyclopentadienyliodoiron(II) 以 not given 为溶剂， 生成 dicarbonylcyclopentadienyl(m-trifluoromethylphenyl)iron
  参考文献：
  名称：

  Arylation of Styrenes with Aryliron Complexes [CpFe(CO)₂Ar]

  摘要：

  Treatment of aryliron complexes [CpFe(CO)(2)Ar] with styrenes in boiling xylene affords the corresponding stilbenes. The aryliron complexes, which become active upon heating, serve as arylating agents in the reaction.

  DOI：

  10.1021/om1001952

文献信息

• Effective Transmetalation from Gold to Iron or Ruthenium
  作者：A. Stephen K. Hashmi、Lise Molinari

  DOI：10.1021/om200360q

  日期：2011.7.11

  The transmetalation of aryl, alkynyl, and alkyl groups from organogold compounds to iron complexes offers an efficient synthesis of organoiron complexes under very mild conditions. This method could be extended to ruthenium complexes.

  芳基，炔基和烷基基团从有机金化合物到铁配合物的金属转移，可以在非常温和的条件下有效地合成有机铁配合物。该方法可以扩展到钌配合物。
• Synthesis of Functionalized Aryliron Complexes [CpFe(CO)₂Ar] by Copper-Mediated Transmetalation between [CpFe(CO)₂I] and Aryltin Reagents
  作者：Shigeo Yasuda、Hideki Yorimitsu、Koichiro Oshima

  DOI：10.1021/om900964e

  日期：2010.1.11

  Transmetalation between [CpFe(CO)(2)I] and aryltin reagents in the presence of copper salts yields the corresponding aryliron complexes [CpFe(CO)(2)Ar]. The high functional group compatibility of this copper-mediated reaction enables us to obtain [CpFe(CO)AI having an acetyl or formyl group, which cannot be prepared by the previous methods with arylzinc or arylboron reagents under palladium catalysis.
• Synthesis of Functionalized Aryliron Complexes by Palladium-Catalyzed Transmetalation between [CpFe(CO)₂I] and Arylzinc or Arylboron Reagents
  作者：Yoshihiro Asada、Shigeo Yasuda、Hideki Yorimitsu、Koichiro Oshima

  DOI：10.1021/om800916r

  日期：2008.12.8

  Transmetalation between [CpFe(CO)(2)I] and arylzinc reagents or arylboronic acids under palladium catalysis yields the corresponding aryliron complexes [CpFe(CO)(2)Ar]. The reactions offer easy and reliable accesses to a variety of [CpFe(CO)(2)Ar] species bearing a functionalized aryl group.