trans-(benzimidazole-κN)diiodo(3-isopropylbenzothiazolin-2-ylidene)palladium(II) | 1225030-98-7

• 英文名称: trans-(benzimidazole-κN)diiodo(3-isopropylbenzothiazolin-2-ylidene)palladium(II)
• CAS: 1225030-98-7
• 化学式: C₁₇H₁₇I₂N₃PdS
• 分子量: 655.637
• InChiKey: PZFNUJUPDSJBKE-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  苯并咪唑 、 diiodo(μ-diiodo)bis(3-isopropylbenzothiazolin-2-ylidene)dipalladium(II) 以 二氯甲烷 为溶剂， 以82%的产率得到trans-(benzimidazole-κN)diiodo(3-isopropylbenzothiazolin-2-ylidene)palladium(II)
  参考文献：
  名称：

  Benzothiazolin‐2‐ylidene and Azole Mixed‐Ligand Complexes of Palladium

  摘要：

  AbstractA series of mixed‐ligand, mononuclear complexes trans‐[PdX2(NSHC)(azole)] [NSHC = N,S‐heterocyclic carbene; azole = imidazole, 1‐(2,4,6‐trimethylphenyl)‐1H‐imidazole, benzimidazole, benzothiazole and benzoxazole] have been prepared and characterised by X‐ray single‐crystal diffraction. These complexes catalyse the sp2–sp3 cross‐coupling of fluoroaryl halides with arylboronic acid to give diarylmethanes with good yields and high turnovers. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

  DOI：

  10.1002/ejic.200900447
• 作为试剂：
  描述：

  4-甲苯硼酸 、 溴甲苯 在 trans-(benzimidazole-κN)diiodo(3-isopropylbenzothiazolin-2-ylidene)palladium(II) 、 potassium carbonate 作用下， 以 水 、 N,N-二甲基甲酰胺 为溶剂， 反应 17.0h， 以100%的产率得到4-甲基二苯甲烷
  参考文献：
  名称：

  Benzothiazolin‐2‐ylidene and Azole Mixed‐Ligand Complexes of Palladium

  摘要：

  AbstractA series of mixed‐ligand, mononuclear complexes trans‐[PdX2(NSHC)(azole)] [NSHC = N,S‐heterocyclic carbene; azole = imidazole, 1‐(2,4,6‐trimethylphenyl)‐1H‐imidazole, benzimidazole, benzothiazole and benzoxazole] have been prepared and characterised by X‐ray single‐crystal diffraction. These complexes catalyse the sp2–sp3 cross‐coupling of fluoroaryl halides with arylboronic acid to give diarylmethanes with good yields and high turnovers. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

  DOI：

  10.1002/ejic.200900447