| 468058-98-2

• CAS: 468058-98-2
• 化学式: C₂₆H₄₀O₁₆P₄Ru₄
• 分子量: 1136.77
• InChiKey: UHRXKKPMJKJADK-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  十二羰基三钌 、 丙二酸 、 三甲基膦 以 四氢呋喃 为溶剂， 以74%的产率得到
  参考文献：
  名称：

  Synthesis, Structures, and Solvent-Occlusion Properties of a Molecular Loop and a Molecular Square Using Tetracarbonyl- and Diphosphine-Ligated Diruthenium(I) as Building Blocks and Dicarboxylates as Linkers

  摘要：

  The reaction of [Ru-3(CO)(12)] with malonic acid or oxalic acid, followed by the addition of PMe3, yielded {[Ru-2(CO)(4)(PMe3)(2)](mu-O2CCH2CO2)}(2) (1) and {[Ru-2(CO)(4)(PMe3)(2)](mu-O2CCO2)}(4) (2), respectively. The molecular structures of both 1 and 2 were determined by single-crystal X-ray diffraction to reveal that 1 is a molecular loop, while 2 is the first example of molecular squares containing {Ru-2(CO)(4)(PR3)(2)} building blocks.

  DOI：

  10.1021/om020360q