[Ru(BINAP)H(η6-benzene)]OTf | 467430-25-7

• 英文名称: [Ru(BINAP)H(η6-benzene)]OTf
• 英文别名: benzene;[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;ruthenium(1+) monohydride;trifluoromethanesulfonate
• CAS: 467430-25-7；528857-01-4
• 化学式: CF₃O₃S*C₅₀H₃₉P₂Ru
• 分子量: 951.948
• InChiKey: PUSQYHIOADDIKH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [Ru(BINAP)H(η6-benzene)]OTf 、 三苯基膦 以 1,2-二氯乙烷 为溶剂， 以95%的产率得到[Ru(BINAP)H(triphenylphosphine)]OTf*H2O
  参考文献：
  名称：

  Binap as an 8e arene-mono-phosphine donor to Ru(II)

  摘要：

  The reaction of the cationic hydride complex [RuH(eta(6)-benzene)(Binap)]CF3SO3 with PPh3 at 80 degreesC afforded complex 4 in excellent yield. The reaction with tri(p-tolyl) phosphine afforded an analogous compound, 5. After loss of the complexed benzene, the Ru-cation generated chooses to stabilize itself by coordinating the proximate naphthyl ring at the expense of one of the two phosphorus donors. The solid-state structure of 4 is reported and reveals that the eta(6) arene is strongly distorted towards a eta(4)-mode. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00393-1
• 作为产物：
  描述：

  三氟甲磺酸 、 苯 、 Ru(OAc)2((S)-BINAP) 以 异丙醇 为溶剂， 以94%的产率得到[Ru(BINAP)H(η6-benzene)]OTf
  参考文献：
  名称：

  A Facile Synthesis of a Wide Variety of Cationic Ruthenium Hydrido-Arene Complexes of binap (=1,1′-Binaphthalene-2,2′-diylbis(diphenylphosphane)) and MeObiphep (=6,6′-Dimethoxybiphenyl-2,2′-diylbis(diphenylphosphane))

  摘要：

  A straightforward high-yield synthetic route to the cationic hydrido-arene complexes [RuH(eta(6)-arene)(binap or MeO-biphep)](CF3SO3), with a variety of arenes containing both donor and acceptor substituents, is described. C-13-NMR Data for these complexes are reported. Several of these Ru-complexes have been used as transfer-hydrogenation catalysts in the reduction of acetophenone.

  DOI：

  10.1002/1522-2675(200211)85:11<3937::aid-hlca3937>3.0.co;2-x