| 1338929-92-2

• CAS: 1338929-92-2
• 化学式: C₂₈H₃₇ClN₂Pd
• 分子量: 543.488
• InChiKey: WZKLAGFOTKBIOP-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (二氯碘)-苯 、 以 氘代氯仿 为溶剂， 以83%的产率得到dichloro(4,4'-di-tert-butyl-2,2'-bipyridine)palladium(II)
  参考文献：
  名称：

  C–H Bond Activation at Palladium(IV) Centers

  摘要：

  This communication describes the first observation and study of C-H activation at a Pd-IV center. This transformation was achieved by designing model complexes in which the rate of reductive elimination is slowed relative to that of the desired C-H activation process. Remarkably, the C-H activation reaction can proceed under mild conditions and with complementary site selectivity to analogous transformations at Pd-II. These results provide a platform for incorporating this new reaction as a step in catalytic processes.

  DOI：

  10.1021/ja2051099