| 354111-33-4

• CAS: 354111-33-4
• 化学式: C₆₄H₉₇ClN₄O₃₀Pd
• 分子量: 1544.36
• InChiKey: HVRWFXWOGXJEFG-FDYIOXHASA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二(氰基苯)二氯化钯 、 2,2'-bipyridyl-6,6'-dicarbonyl-A,D-capped 6A,6D-diamino-6A,6D-dideoxy-hexadeca-O-methyl-α-cyclodextrin 以 氯仿 为溶剂， 以97%的产率得到
  参考文献：
  名称：

  Anchoring a helical handle across a cavity: the first 2,2′-bipyridyl-capped α-cyclodextrin capable of encapsulating transition metals

  摘要：

  The reaction of 6,6 ' -bis(chlorocarbonyl)-2,2 ' -bipyridine with 6A,6D-diamino-6A,6D-dideoxy-2(A),2(B),2(C),2(D),2(E),2(F),3(A),3(B), 3(C),3(D),3(E),3(F),6(B),6(C),6(E),6(F)-hexadeca-O-methylcyclo maltohexaose (1) afforded the corresponding capped cyclodextrin derivative (LH) in which the nitrogen atoms are forced to point towards the cavity interior. As shown by a single crystal X-ray diffraction study, the capping handle adopts a helical shape. In silver(I) and palladium(II) complexes derived from LH, the metal centre is encapsulated and positioned at the entrance of the CD receptor. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0277-5387(01)00727-6