1-carboxy-3-ethylcyclopentadienyltricarbonylmanganese | 32965-90-5

• 英文名称: 1-carboxy-3-ethylcyclopentadienyltricarbonylmanganese
• 英文别名: 1,3-ethyl(carboxy)cymantrene
• CAS: 32965-90-5
• 化学式: C₁₁H₉MnO₅
• 分子量: 276.127
• InChiKey: DGWWIVLOKYIQMT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  undecacarbonyl(acetonitrile)triosmium 、 1-carboxy-3-ethylcyclopentadienyltricarbonylmanganese 在 十二/十四烷基二甲基氧化胺 作用下， 以 甲醇 、 乙腈 为溶剂， 以68%的产率得到1,1,1,1,2,2,2,3,3,3-decacarbonyl-1,2-μ-hydrido-1,2-μ,eta.2-(O,O')-(1-carboxy-3-ethylcyclopentadienyltricarbonylmanganese)triangulotriosmium
  参考文献：
  名称：

  Photochemical reaction of the heterometallic complex (μ-H)Os3{μ-O2CC5H4Mn(CO)3}(CO)10 with triphenylphosphine

  摘要：

  Photolysis of the heterometallic complex (mu-H)Os-3{mu-O2CC5H4Mn(CO)(3)}(CO)(10) together with PPh3 results in replacement of the CO groups by PPh3 both at the Mn atom and in the Os-3 metallocycle to afford the complexes (mu-H)Os-3{mu-O2CC5H4Mn(CO)(2)PPh3}(CO)(10), (mu-H)Os-3{mu-O2CC5H4Mn(CO)(3)}(CO)(9)PPh3, and (mu-H)Os-3{mu-O2CC5H4Mn(CO)(2)PPh3}(CO)(9)PPh3 (two isomers). The reaction is also accompanied by the partial removal of the Mn(CO)(3) group followed by the protonation of the cyclopentadienyl group and formation of triosmium clusters (mu-H)Os-3(mu-O2CC5H4R)(CO)(10) (R = H, Et).

  DOI：

  10.1007/bf02495496
• 作为产物：
  描述：

  (η5-C5H4Et)Mn(CO)3 、 二氧化碳 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 以48%的产率得到1-carboxy-3-ethylcyclopentadienyltricarbonylmanganese
  参考文献：
  名称：

  Photochemical reaction of the heterometallic complex (μ-H)Os3{μ-O2CC5H4Mn(CO)3}(CO)10 with triphenylphosphine

  摘要：

  Photolysis of the heterometallic complex (mu-H)Os-3{mu-O2CC5H4Mn(CO)(3)}(CO)(10) together with PPh3 results in replacement of the CO groups by PPh3 both at the Mn atom and in the Os-3 metallocycle to afford the complexes (mu-H)Os-3{mu-O2CC5H4Mn(CO)(2)PPh3}(CO)(10), (mu-H)Os-3{mu-O2CC5H4Mn(CO)(3)}(CO)(9)PPh3, and (mu-H)Os-3{mu-O2CC5H4Mn(CO)(2)PPh3}(CO)(9)PPh3 (two isomers). The reaction is also accompanied by the partial removal of the Mn(CO)(3) group followed by the protonation of the cyclopentadienyl group and formation of triosmium clusters (mu-H)Os-3(mu-O2CC5H4R)(CO)(10) (R = H, Et).

  DOI：

  10.1007/bf02495496