[(η5:σ-(CH3)2C(C9H6)(C2B10H10))Zr(N(CH3)2)2] | 386285-20-7

• 英文名称: [(η5:σ-(CH3)2C(C9H6)(C2B10H10))Zr(N(CH3)2)2]
• 英文别名: [η5:σ-Me2C(C9H6)(C2B10H10)]Zr(NMe2)2
• CAS: 386285-20-7
• 化学式: C₁₈H₃₄B₁₀N₂Zr
• 分子量: 477.815
• InChiKey: MCIOGOFNWCWRIO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(η5:σ-(CH3)2C(C9H6)(C2B10H10))Zr(N(CH3)2)2] 、 N,N'-二甲基-1,3-丙二胺 以 甲苯 为溶剂， 以62%的产率得到[η5:η5-Me2C(C9H6)(C2B9H10)]Zr[η2-N(Me)(CH2)3NHMe]
  参考文献：
  名称：

  Facile Synthesis of ansa-Zirconocenes Incorporating a Linked Dicarbollyl Ligand via Direct Deboration of Zirconocene Carboranyl Complexes

  摘要：

  ansa-Zirconocene amides incorporating a Me2C-linked cyclopentadienyl-dicarbollyl or indenyl-dicarbollyl ligand were conveniently prepared from direct deboration of the corresponding carboranyl metal complexes using diamines as deboration agents. This represents a new methodology for the preparation of metal dicarbollides.

  DOI：

  10.1021/om200245g
• 作为产物：
  描述：

  四(二甲氨基)锆 、 以 甲苯 为溶剂， 以86%的产率得到[(η5:σ-(CH3)2C(C9H6)(C2B10H10))Zr(N(CH3)2)2]
  参考文献：
  名称：

  具有约束几何形状的碳硼烷配体的第4族金属配合物的合成，结构表征和烯烃聚合行为

  摘要：

  几种新的第4族金属的酰胺络合物与最近开发的限制几何构型碳硼烷配位体，[η 5：σ-ME 2 A（C 9 H ^ 6）（C 2乙10 ħ 10）] M（NR 2）2和[η 5：σ-ME 2 A（C 5 H ^ 4）（C 2乙10 ħ 10）] M（NR 2）2（A = C，硅; M =钛，锆; R =甲基，乙基），是在制备通过M（NR 2）4的胺消除反应获得良好的收率和甲苯中的相应中性配体。用2.5当量的Me酰胺配合物的治疗2 NH·HCl的或Me 3 N·盐酸导致相应的氯化物配合物的高产率，[{η 5：σ-ME 2 A（C 9 H ^ 6）（C 2乙10 ħ 10）}的ZrCl（μ-Cl）的1.5 ] 2 -（A = C，Si）的，这也可以由使用ZrCl之间等摩尔反应制备4（THF）2和[我2 C（ç 9 ħ 6） （C 2 B 10 H 10）] Li 2。相反，过量我3的SiCl只能转换[η

  DOI：

  10.1021/om010642a

文献信息

• Multiple Insertion of Unsaturated Molecules into the Zr−N Bonds of [<i>η</i>⁵:<i>σ</i>-Me₂A(C₉H₆)(C₂B₁₀H₁₀)]Zr(NMe₂)₂ (A = C, Si)
  作者：Haiping Wang、Hung-Wing Li、Zuowei Xie

  DOI：10.1021/om0304255

  日期：2003.10.1

  The compounds [eta(5):sigma-Me(2)A(C9H6)(C2B10H10)]Zr(NMe2)(2) (A = C, Si) reacted with CS2, PhCN, CH2=CHCN, (BuNCS)-Bu-n, and PhNCO to give the mono-, di-, and triinsertion products, depending upon the substrates. These unsaturated substances inserted exclusively into the Zr-N bonds, and the Zr-C(cage) bond remains intact in all reactions. It is believed that the preference of Zr-N over Zr-C(cage) insertion is governed by steric factors. The metal amide compounds also initiated the polymerization of CH2=CHCN to produce poly(acrylonitrile) and catalyzed the trimerization of PhNCO. On the other hand, they reacted with methyl methacrylate to afford [eta(5):sigma-Me(2)A(C9H6)(C2B10H10)}Zr(OCH3)(mu-OCH3)](2) and CH2=C(Me)CONMe2. All insertion products were fully characterized by various spectroscopic data, elemental analyses, and X-ray diffraction studies.
• Synthesis, Structure, and Bonding of a Zirconocene-1,2-Dehydro-o-carborane Complex
  作者：Haiping Wang、Hung-Wing Li、Xin Huang、Zhenyang Lin、Zuowei Xie

  DOI：10.1002/anie.200351892

  日期：2003.9.22