[zirconium(dichloride)(N-(3,5-diiodo-salicylidene)cycloheptylamine(-H))2] | 1262508-44-0

• 英文名称: [zirconium(dichloride)(N-(3,5-diiodo-salicylidene)cycloheptylamine(-H))2]
• CAS: 1262508-44-0
• 化学式: C₂₈H₃₂Cl₂I₄N₂O₂Zr
• 分子量: 1098.32
• InChiKey: OAXOJKCQSLSCED-IEYSPWQYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N-(3,5-diiodo-salicylidene)cycloheptylamine 、 氯化锆(IV) 在 n-BuLi 作用下， 以 四氢呋喃 为溶剂， 生成 [zirconium(dichloride)(N-(3,5-diiodo-salicylidene)cycloheptylamine(-H))2]
  参考文献：
  名称：

  Catalysts for UHMWPE and UHMWPE-copolymers

  摘要：

  Classic inorganic and more recent organometallic compounds capable of polymerizing ethylene to ultra high molecular are compared. Activated catalysts showed varying degrees of productivity when challenged with co-monomers. The general activity trend followed TiCl3 < Mg/Si-TiCl3 < metallocenes. A new phenoxyimine catalyst complex N-(3,5-diiodosalicylidene) cycloheptylamine titanium dichloride was useful in making UHMWPE and compared to previously reported phenoxyimine catalyst structures capable of living polyolefin polymerizations. (C) 2010 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.08.050