(1,3,5-trimethyl-1,3,5-triazacyclohexane)Cr(CO)3 | 128085-00-7

• 英文名称: (1,3,5-trimethyl-1,3,5-triazacyclohexane)Cr(CO)3
• CAS: 128085-00-7；190122-74-8
• 化学式: C₉H₁₅CrN₃O₃
• 分子量: 265.232
• InChiKey: BSTRHGZUJJOYBV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (1,3,5-trimethyl-1,3,5-triazacyclohexane)Cr(CO)3 、 三(3,5-二甲基-1-吡唑基)甲烷 以 丙酮 为溶剂， 以69%的产率得到tris(3,5-dimethyl-1-pyrazolyl)methane chromium tricarbonyl(0)
  参考文献：
  名称：

  Armanasco, Nicole L.; Baker, Murray V.; North, Michael R., Journal of the Chemical Society, Dalton Transactions, 1997, # 8, p. 1363 - 1368

  摘要：

  DOI：
• 作为产物：
  描述：

  1,3,5-三甲基己羟基-1,3,5-三嗪 、 六羰基铬 以 二丁醚 为溶剂， 生成 (1,3,5-trimethyl-1,3,5-triazacyclohexane)Cr(CO)3
  参考文献：
  名称：

  Gemischte carbonylkomplexe des Cro und des Moo mit organo-stickstoffverbindungen

  摘要：

  DOI：

  10.1016/s0040-4039(01)99429-8

文献信息

• Chromium complexes of hydroxyl-functionalised 1,3,5-triazacyclohexanes
  作者：Murray V. Baker、David H. Brown、Brian W. Skelton、Allan H. White

  DOI：10.1039/a900122k

  日期：——

  The chromium co-ordination chemistry of three 1,3,5-triazacyclohexanes bearing hydroxyl-functionalised substituents on nitrogen has been explored. The complexes [CrL3(C3H6N3R3)] (L = CO, R = CH2CH2OH, CH2CH2CH2OH or o-hydroxybenzyl; L  = Br, R = CH2CH2CH2OH) have been prepared. Characterisation of the carbonyl complexes by spectroscopic and structural methods indicated that the triazacyclohexanes co-ordinate

  已经研究了在氮上带有羟基官能化取代基的三个1,3,5-三氮杂环己烷的铬配位化学。配合物[CrL 3（C 3 H 6 N 3 R 3）]（L = CO，R = CH 2 CH 2 OH，CH 2 CH 2 CH 2 OH或邻羟基苄基； L = Br，R = CH 2 CH 2通道2OH）已经准备好了。通过光谱和结构方法表征羰基配合物表明，三氮杂环己烷仅通过三个氮原子与铬中心配位。1,3,5-三（邻羟基苄基）-1,3,5-三氮杂环己烷和[Cr（CO）3（C 3 H 6 N 3 R 3）]的晶体结构测定（R = CH 2 CH 2 OH或CH 2 CH 2 CH 2 OH）。
• Group 6 metal complexes of 1,3,5-tri(4-pentynyl)-1,3,5-triazacyclohexane
  作者：Murray V. Baker、David H. Brown、Brian W. Skelton、Allan H. White

  DOI：10.1039/a908349i

  日期：——

  1,3,5-Tri(4-pentynyl)-1,3,5-triazacyclohexane (tptach), a 1,3,5-triazacyclohexane ligand with three pendant alkyne groups, was synthesized. The metal tricarbonyl adducts [Cr(CO)3(tptach)] and [Mo(CO)3(tptach)], featuring a tptach co-ordinated to the metal centre via only the three nitrogen atoms, were prepared by reaction of tptach with reactive sources of “M(CO)3”. The chromium trichloride adduct [CrCl3(tptach)] was synthesized in low yield via the reaction of tptach with [CrCl3(thf)3]. Structural studies of [CrCl3(tptach)] and another chromium trihalide–tach adduct, [CrBr3(tmtach)] (tmtach = 1,3,5-trimethyl-1,3,5-triazacyclohexane), were made.

  1,3,5-三(4-戊炔基)-1,3,5-三氮杂环己烷（ptach）是一种带有三个炔基的 1,3,5-三氮杂环己烷配体。金属三羰基加合物[Cr(CO)3(tptach)]和[Mo(CO)3(tptach)]是通过 tptach 与活性源 "M(CO)3 "反应制备的，其特点是 tptach 仅通过三个氮原子与金属中心配位。三氯化铬加合物[CrCl3(ptach)]是通过 tptach 与[CrCl3(thf)3]反应合成的，产量较低。对[CrCl3(tptach)]和另一种三卤化铬-tach 加合物[CrBr3(tmtach)]（tmtach = 1,3,5-三甲基-1,3,5-三氮杂环己烷）进行了结构研究。
• An unexpected pentacarbonyl chromium complexation of a cyano group of the ABC core of cephalotaxine
  作者：Laith Quteishat、Armen Panossian、Franck Le Bideau、Rana Alsalim、Pascal Retailleau、Claire Troufflard、Eric Rose、Françoise Dumas

  DOI：10.1016/j.jorganchem.2014.10.040

  日期：2015.1

  A new penta-carbonyl chromium(0) complex of the type [Cr(CO)(5)(L)] (L = tetracyclic pyrrolobenzazepine unit 3) was surprisingly obtained by reacting [Cr(CO)(3)(naphthalene)] or [Cr(CO)(3)(tmtach)] with the tetracyclic pyrrolobenzazepine unit 3 in octane-ether/THF-solvent mixtures or acetone under ambient temperature or reflux. The new complex 13 has been characterized by spectral analysis including IR, H-1 and C-13 NMR data. For comparison purposes, the safrole-tricarbonyl chromium(0) complex 12 was prepared and characterized. X-ray diffraction analyses of both complexes were determined. Based on the above data, an octahedral structure has been assigned to the new complex 13. (C) 2014 Elsevier B.V. All rights reserved.
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Cr: Org.Verb., 1.1.2.1.5.2, page 66 - 70
  作者：

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Cr: Org.Verb., 1.1.2.1.9, page 91 - 97
  作者：

  DOI：——

  日期：——