[Fe2(CO)6(μ-S2C=CHC(O)C6H4OMe)] | 623149-67-7

• 英文名称: [Fe2(CO)6(μ-S2C=CHC(O)C6H4OMe)]
• CAS: 623149-67-7
• 化学式: C₁₆H₈Fe₂O₈S₂
• 分子量: 504.061
• InChiKey: WZYSABYPNOBWQA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  diiron nonacarbonyl 、 [Fe2(CO)6(μ-S2C=CHC(O)C6H4OMe)] 以 四氢呋喃 为溶剂， 以21.3%的产率得到[Fe(CO)4(μ-(MeOC6H4C(O)CH=CS2)Fe2(CO)6)]
  参考文献：
  名称：

  Reactivity of Fe3(CO)12 towards thiols containing an α,β-unsaturated ketone system

  摘要：

  The unsaturated derivatives [Fe-2(CO)(6)(mu-S2C=CHC(O)C6H4X)] (X = F, OMe) have been isolated by reaction of [(HS)(2)C = CHC(O)C6H4X] (X = F, OMe) with Fe-3(CO)(12) in dried THF. Addition of Fe-2(CO)(9) to a solution of [Fe-2(CO)(6)(mu-S2C = CHC(O)C6H4OMe)] affords [Fe(CO)(4){mu-(OMe)C6H4C(O)CH = C(S)(2)Fe-2(CO)(6)}]. The new compounds have been characterised by analytical and spectroscopic data and the crystal structure of [Fe-2(CO)(6)(mu-S2C = CHC(O)C6H4F)] has been solved by X-ray diffraction. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00194-4
• 作为产物：
  描述：

  十二羰基三铁 、 3-(4-methoxyacetobenzophenylidene)-5-(4-methoxyacetobenzophenyl)-1,2,4-trithiol 在 ONMe₃ 作用下， 以 四氢呋喃 为溶剂， 生成 [Fe2(CO)6(μ-S2C=CHC(O)C6H4OMe)]
  参考文献：
  名称：

  Reactivity of Fe3(CO)12 towards thiols containing an α,β-unsaturated ketone system

  摘要：

  The unsaturated derivatives [Fe-2(CO)(6)(mu-S2C=CHC(O)C6H4X)] (X = F, OMe) have been isolated by reaction of [(HS)(2)C = CHC(O)C6H4X] (X = F, OMe) with Fe-3(CO)(12) in dried THF. Addition of Fe-2(CO)(9) to a solution of [Fe-2(CO)(6)(mu-S2C = CHC(O)C6H4OMe)] affords [Fe(CO)(4){mu-(OMe)C6H4C(O)CH = C(S)(2)Fe-2(CO)(6)}]. The new compounds have been characterised by analytical and spectroscopic data and the crystal structure of [Fe-2(CO)(6)(mu-S2C = CHC(O)C6H4F)] has been solved by X-ray diffraction. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00194-4