[Ru(2,2':6',2''-terpyridine)(2,2'-dipyridyl ketone)(Cl)](ClO4) | 864359-74-0

• 英文名称: [Ru(2,2':6',2''-terpyridine)(2,2'-dipyridyl ketone)(Cl)](ClO4)
• CAS: 864359-74-0
• 化学式: C₂₆H₁₉ClN₅ORu*ClO₄
• 分子量: 653.443
• InChiKey: NOAIQJUGFFIFEM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ru(2,2':6',2''-terpyridine)(2,2'-dipyridyl ketone)(Cl)](ClO4) 在 HNO₃ 作用下， 以 高氯酸 、 水 、 硝酸 、 乙腈 为溶剂， 生成 [Ru(2,2':6',2''-terpyridine)(2,2'-dipyridyl ketone)(NO)](ClO4)3
  参考文献：
  名称：

  Complex Series [Ru(tpy)(dpk)(X)]ⁿ⁺ (tpy = 2,2‘:6‘,2‘ ‘-Terpyridine; dpk = 2,2‘-Dipyridyl Ketone; X = Cl^-, CH₃CN, NO₂^-, NO⁺, NO^•, NO^-):  Substitution and Electron Transfer, Structure, and Spectroscopy

  摘要：

  The complex framework [Ru(tpy)(dpk)](2+) has been used to study the generation and reactivity of the nitrosyl complex [Ru(tpy)(dpk)(NO)(3+) ([4](3+)). Stepwise conversion of the chloro complex [Ru(tpy)(dpk)(Cl)](+) ([1](+)) via [Ru(tpy)(dpk)(CH3CN)](2+) ([2](2+)) and the nitro compound [Ru(tpy)(dpk)(NO2)](+) ([3](+)) yielded [4](3+); all four complexes were structurally characterized as perchlorates. Electrochemical oxidation and reduction was investigated as a function of the monodentate ligand as was the IR and UV-vis spectroscopic response (absorption/emission). The kinetics of the conversion [4](3+)/[3](+) in aqueous environment were also studied. Two-step reduction of [4](3+) was monitored via EPR, UV-vis, and IR (v(NO), v(CO)) spectroelectrochemistry to confirm the {RuNO}(7) configuration of [4](2+) and to exhibit a relatively intense band at 505 nm for [4](+), attributed to a ligand-to-ligand transition originating from bound NO-.

  DOI：

  10.1021/ic050533e
• 作为产物：
  描述：

  2-二吡啶基酮 、 Ru(tpy)(Cl)₃ 、 sodium perchlorate 在 LiCl 、 (C₂H₅)3N 作用下， 以 乙醇 为溶剂， 以76%的产率得到[Ru(2,2':6',2''-terpyridine)(2,2'-dipyridyl ketone)(Cl)](ClO4)
  参考文献：
  名称：

  Complex Series [Ru(tpy)(dpk)(X)]ⁿ⁺ (tpy = 2,2‘:6‘,2‘ ‘-Terpyridine; dpk = 2,2‘-Dipyridyl Ketone; X = Cl^-, CH₃CN, NO₂^-, NO⁺, NO^•, NO^-):  Substitution and Electron Transfer, Structure, and Spectroscopy

  摘要：

  The complex framework [Ru(tpy)(dpk)](2+) has been used to study the generation and reactivity of the nitrosyl complex [Ru(tpy)(dpk)(NO)(3+) ([4](3+)). Stepwise conversion of the chloro complex [Ru(tpy)(dpk)(Cl)](+) ([1](+)) via [Ru(tpy)(dpk)(CH3CN)](2+) ([2](2+)) and the nitro compound [Ru(tpy)(dpk)(NO2)](+) ([3](+)) yielded [4](3+); all four complexes were structurally characterized as perchlorates. Electrochemical oxidation and reduction was investigated as a function of the monodentate ligand as was the IR and UV-vis spectroscopic response (absorption/emission). The kinetics of the conversion [4](3+)/[3](+) in aqueous environment were also studied. Two-step reduction of [4](3+) was monitored via EPR, UV-vis, and IR (v(NO), v(CO)) spectroelectrochemistry to confirm the {RuNO}(7) configuration of [4](2+) and to exhibit a relatively intense band at 505 nm for [4](+), attributed to a ligand-to-ligand transition originating from bound NO-.

  DOI：

  10.1021/ic050533e