CpFe(C6H4Br-4)(CO)2 | 183867-88-1

• 英文名称: CpFe(C6H4Br-4)(CO)2
• 英文别名: [CpFe(CO)2C6H4-4-F]
• CAS: 183867-88-1
• 化学式: C₁₃H₉BrFeO₂
• 分子量: 332.964
• InChiKey: JXTVCXFSAHIUMZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  苯乙烯 、 CpFe(C6H4Br-4)(CO)2 以 5,5-dimethyl-1,3-cyclohexadiene 为溶剂， 反应 12.0h， 以58%的产率得到1-bromo-4-styrylbenzene
  参考文献：
  名称：

  Arylation of Styrenes with Aryliron Complexes [CpFe(CO)₂Ar]

  摘要：

  Treatment of aryliron complexes [CpFe(CO)(2)Ar] with styrenes in boiling xylene affords the corresponding stilbenes. The aryliron complexes, which become active upon heating, serve as arylating agents in the reaction.

  DOI：

  10.1021/om1001952
• 作为产物：
  描述：

  dicarbonylcyclopentadienyliodoiron(II) 以 not given 为溶剂， 生成 CpFe(C6H4Br-4)(CO)2
  参考文献：
  名称：

  Arylation of Styrenes with Aryliron Complexes [CpFe(CO)₂Ar]

  摘要：

  Treatment of aryliron complexes [CpFe(CO)(2)Ar] with styrenes in boiling xylene affords the corresponding stilbenes. The aryliron complexes, which become active upon heating, serve as arylating agents in the reaction.

  DOI：

  10.1021/om1001952

文献信息

• Synthesis of Aryliron Complexes by Palladium-Catalyzed Transmetalation between [CpFe(CO)₂I] and Aryl Grignard Reagents and Their Chemistry Directed toward Organic Synthesis
  作者：Shigeo Yasuda、Hideki Yorimitsu、Koichiro Oshima

  DOI：10.1021/om800560m

  日期：2008.8.1

  Palladium-catalyzed transmetalation between [CpFe(CO)2I] and aryl Grignard reagents emerges as a new method for the synthesis of [CpFe(CO)2Ar]. The aryliron complexes thus formed are useful arylmetal reagents that become active upon oxidation or UV irradiation.

  钯催化[CpFe（CO）2 I]与芳基格氏试剂之间的金属转移反应是一种合成[CpFe（CO）2 Ar]的新方法。如此形成的芳基铁配合物是有用的芳基金属试剂，其在氧化或紫外线照射下具有活性。
• Synthesis of Functionalized Aryliron Complexes by Palladium-Catalyzed Transmetalation between [CpFe(CO)₂I] and Arylzinc or Arylboron Reagents
  作者：Yoshihiro Asada、Shigeo Yasuda、Hideki Yorimitsu、Koichiro Oshima

  DOI：10.1021/om800916r

  日期：2008.12.8

  Transmetalation between [CpFe(CO)(2)I] and arylzinc reagents or arylboronic acids under palladium catalysis yields the corresponding aryliron complexes [CpFe(CO)(2)Ar]. The reactions offer easy and reliable accesses to a variety of [CpFe(CO)(2)Ar] species bearing a functionalized aryl group.