methyl[2-[[(1-methylethyl)imino-κN]methyl]phenyl-κC](carbonyl)bis(trimethylphosphine)iron(II) | 1140507-71-6

• 英文名称: methyl[2-[[(1-methylethyl)imino-κN]methyl]phenyl-κC](carbonyl)bis(trimethylphosphine)iron(II)
• CAS: 1140507-71-6
• 化学式: C₁₈H₃₃FeNOP₂
• 分子量: 397.261
• InChiKey: NFXSWQIXNSHYQA-WEBCDHPFSA-N

物化性质

• 熔点：
  131-133 °C

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  一氧化碳 、 methyl[2-[[(methylethyl)imino-κN]methyl]phenyl-κC]tris(trimethylphosphine)iron(II) 以 正戊烷 为溶剂， 以58%的产率得到methyl[2-[[(1-methylethyl)imino-κN]methyl]phenyl-κC](carbonyl)bis(trimethylphosphine)iron(II)
  参考文献：
  名称：

  C−H Activation of Imines by Trimethylphosphine-Supported Iron Complexes and Their Reactivities

  摘要：

  First examples of ortho-metalated mono-iron complexes of monodentate N-donor ligands via C-H activation have been synthesized. Treatment of benzylicimines and ketimines with Fe(CH3)(2)(PMe3)(4) and Fe(PMe3)(4) under mild conditions results in ortho-metalated hydrido-iron(II) and methyl-iron(II) complexes in high yields, and their iodomethane reactions give thermally stable iodo-iron(II) compounds, which are interesting versatile nucleophiles in organometallic and organic chemistry.

  DOI：

  10.1021/om800828j