(η⁵-cyclopentadienyl)(η6-iodobenzene)ruthenium(II) hexafluoridophosphate | 174498-93-2

• 英文名称: (η⁵-cyclopentadienyl)(η6-iodobenzene)ruthenium(II) hexafluoridophosphate
• 英文别名: (η(5)-2,4-cyclopentadien-1-yl)(η(6)-iodobenzene)ruthenium hexafluorophosphate
• CAS: 174498-93-2
• 化学式: C₁₁H₁₀IRu*F₆P
• 分子量: 515.139
• InChiKey: XECRLUCTFHDHHR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  tributylstannylethynylferrocene 、 (η⁵-cyclopentadienyl)(η6-iodobenzene)ruthenium(II) hexafluoridophosphate 在 tris-(dibenzylideneacetone)dipalladium(0) 、 三苯胂 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 20.08h， 以67%的产率得到(η⁵-cyclopentadienyl)(ferrocenylethynyl-η6-benzene)ruthenium(II) hexafluoridophosphate
  参考文献：
  名称：

  Stille Cross-Coupling Reaction with Cationic [(η⁵-Cp)(η⁶-C₆H_6–xI_x)Ru]⁺ Complexes as Key for Ethynyl-Bridged Homo- and Heteronuclear Sandwich Compounds

  摘要：

  The cationic homo- and heteronuclear sandwich complexes (eta(5)-cyclopentadienyl)(ferrocenylethynyl-eta(6)-benzene)ruthenium(II) hexafluoridophosphate (3a), (eta(5)-cyclopentadienyl)(ruthenocenylethynyl-eta(6)-benzene)ruthenium(II) hexafluoridophosphate (3b), (eta(5)-cyclopentadienyl)[1,4-bis(ferrocenylethynyl)-eta(6)-benzene]ruthenium(II) hexafluoridophosphate (4a), (eta(5)-cyclopentadienyl)[1,4-bis(ruthenocenylethynyl)-eta(6)-benzene]ruthenium(II) hexafluoridophosphate (4b), and (eta(5)-cyclopentadienyl)[1,3,5-tris(ferrocenylethynyl)-eta(6)-benzene]ruthenium(II) hexafluoridophosphate (5) were synthesized by means of Stille cross-coupling reaction using tri-n-butyl(metallocenylethynyl)stannane as nucleophile and the appropriate (eta(5)-cyclopentadienyl)(eta(6)-iodobenzene)ruthenium(II) cations as electrophiles. As a catalyst, a Pd(0) complex, furnished with AsPh3 ligands, was applied. The hitherto unknown iodobenzene complexes (eta(5)-cyclopentadienyl)(1,4-eta(6)-diiodobenzene)ruthenium(II) hexafluoridophosphate (1b) and (eta(5)-cyclopentadienyl)(eta(6)-1,3,5-triiodobenzene)ruthenium(II) hexafluoridophosphate (1c) as well as the described cationic homo- and heteronuclear sandwich complexes 3-5 were fully characterized and investigated with respect to the second-harmonic generation by hyper-Rayleigh scattering. For complexes 1b, 1c, 3a, and 5 X-ray structure determinations were performed.

  DOI：

  10.1021/acs.organomet.5b00160
• 作为产物：
  描述：

  cyclopentadienylruthenium(II) trisacetonitrile hexafluorophosphate 、 碘苯 以 1,2-二氯乙烷 为溶剂， 以91%的产率得到(η⁵-cyclopentadienyl)(η6-iodobenzene)ruthenium(II) hexafluoridophosphate
  参考文献：
  名称：

  Towards the synthesis of amino[b,e][1,4]dioxin derivatives via cationic ruthenium complexes

  摘要：

  Double nucleophilic aromatic substitution reactions between N-substituted (eta(6)-1,2-dichlorobenzene)RuCp(+) salts and substituted 1,2-benzenediols have been carried out under mild conditions to prepare N-substituted (eta(6)-dibenzo[b,e][1,4]dioxin)ruthenium(II) complexes. The dibenzodioxin ligands were subsequently liberated by photolysis, with radiation from a sunlamp or from a medium pressure Hg lamp (300 nm).

  DOI：

  10.1016/0022-328x(95)05717-4